{"id":"W1969327495","doi":"10.1021/ja040039u","title":"Reduction of Strained Polycycles:  How Much Strain Can a Pyrene Anion Take?","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Fullerene Chemistry and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Reduction (mathematics); Pyrene; Strain (injury); Ion; Organic chemistry; Physical therapy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001215493,0.0001654446,0.000334543,0.000009259617,0.00008614104,0.00002091777,0.0004966244,0.00009199246,0.00005531042],"category_scores_gemma":[0.00008248502,0.0001235254,0.000586142,0.0003167287,0.0005889274,0.00005746137,0.00006243354,0.0004840948,3.533573e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002651011,"about_ca_system_score_gemma":0.0001990834,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000404777,"about_ca_topic_score_gemma":9.282243e-7,"domain_scores_codex":[0.9988508,0.00001087023,0.000393147,0.0001672998,0.0003587672,0.0002191496],"domain_scores_gemma":[0.9982879,0.00004107848,0.001083537,0.0003232571,0.000133552,0.0001306534],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003403853,0.0001726113,0.00006564707,0.00004515909,0.0001051824,6.114813e-7,0.0003647266,0.0000387543,0.9966481,0.00005316166,0.001268774,0.001203207],"study_design_scores_gemma":[0.0006245013,0.00002615534,0.000173662,0.00008455778,0.00006427779,0.000125563,0.004426749,0.00001044953,0.9920602,0.001995429,0.000279378,0.0001290244],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895431,0.0000490521,0.0001541031,0.009833849,0.00003691628,0.00003320404,0.00007125874,0.00001720864,0.0002613515],"genre_scores_gemma":[0.9962513,0.00006002135,0.002937434,0.0001031983,0.0004837594,0.00000364235,0.00001009728,0.00001856975,0.0001319046],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009730651,"threshold_uncertainty_score":0.5037218,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01120545413489607,"score_gpt":0.2397351019443183,"score_spread":0.2285296478094222,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}