{"id":"W1969329904","doi":"10.1021/om0106231","title":"α-Agostic Interactions in Cp*W(NO)(CH<sub>2</sub>CMe<sub>3</sub>)<sub>2</sub> and Related Nitrosyl Complexes","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Agostic interaction; Chemistry; Crystallography; Ligand (biochemistry); Amide; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.000604053,0.001269248,0.001689118,0.000927353,0.0006267406,0.0004727471,0.0009667973,0.000517161,0.005134098],"category_scores_gemma":[0.0008333263,0.00137176,0.000655764,0.002614613,0.0005298477,0.0008927796,0.0007271194,0.001382335,0.002035847],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005997614,"about_ca_system_score_gemma":0.0002159239,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005878146,"about_ca_topic_score_gemma":0.0008917628,"domain_scores_codex":[0.9936312,0.0002041988,0.00190983,0.001803945,0.0009094616,0.001541389],"domain_scores_gemma":[0.9956119,0.0008210933,0.0007540474,0.001749364,0.0003478959,0.000715673],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001025357,0.0008372707,0.00268026,0.0002007379,0.0006330757,0.000164785,0.0004136291,0.00003262467,0.9593515,0.0002745386,0.000342711,0.03496634],"study_design_scores_gemma":[0.001681209,0.0000869766,0.01086615,0.0002549356,0.0007779446,0.0004625072,0.0006157011,0.0007329224,0.964067,0.001218593,0.01748421,0.001751788],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9875937,0.001250498,0.0001190722,0.000498948,0.0004391345,0.0004023399,0.0002884104,0.0004808398,0.008927079],"genre_scores_gemma":[0.9938722,0.003278257,0.0001561043,0.0002026882,0.0004334818,0.000118631,0.00073223,0.0003385886,0.0008677877],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03321455,"threshold_uncertainty_score":0.9988732,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01344705218618577,"score_gpt":0.2228560360188524,"score_spread":0.2094089838326667,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}