{"id":"W1969331485","doi":"10.1021/jo701524p","title":"Enantioselective Synthesis of the Alcohol Moiety of Dolabriferol","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Enantioselective synthesis; Moiety; Alcohol; Stereochemistry; Chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008607372,0.0001828415,0.0003902881,0.00001563971,0.00007791771,0.000006541871,0.0008966475,0.0002017016,0.001992498],"category_scores_gemma":[0.0005812393,0.0001063142,0.0004322962,0.0004237977,0.0004205731,0.00005591151,0.0001034015,0.0005892093,0.000001324298],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006366326,"about_ca_system_score_gemma":0.0001598285,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006433167,"about_ca_topic_score_gemma":0.000001233137,"domain_scores_codex":[0.998286,0.00002293163,0.0007998363,0.0001086086,0.0005251914,0.0002573939],"domain_scores_gemma":[0.9974439,0.0005921758,0.001025175,0.0004978163,0.0003384397,0.0001025624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001423484,0.0001555162,0.00218899,0.0003548,0.0003365129,0.000004850587,0.0001914875,0.000003913622,0.9958036,0.000006701264,0.0005100306,0.0003012365],"study_design_scores_gemma":[0.0003616981,0.000009768935,0.0006133342,0.0002729384,0.000400652,0.0004051939,0.001000484,0.000004722031,0.9963201,0.0002382039,0.0002651992,0.000107713],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9858656,0.0007182005,0.0002040635,0.0002727745,0.00004143183,0.00002406013,0.00001392235,0.000008826397,0.01285111],"genre_scores_gemma":[0.9987192,0.0001399366,0.00006471237,0.00002290276,0.0002182509,3.329087e-7,4.599129e-7,0.00002103304,0.0008132284],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01285354,"threshold_uncertainty_score":0.9989198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006324496441261775,"score_gpt":0.2168260404078507,"score_spread":0.2105015439665889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}