{"id":"W1969405366","doi":"10.1039/b418940j","title":"Electronic and steric effects in fragmentation reactions of Os<sub>3</sub>(CO)<sub>9</sub>(μ-C<sub>4</sub>Ph<sub>4</sub>)","year":2005,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Steric effects; Fragmentation (computing); Chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005198905,0.0009158651,0.001149777,0.000858994,0.0006175041,0.0001733719,0.0004532892,0.0005458659,0.0005674321],"category_scores_gemma":[0.00007216813,0.001059701,0.0006685871,0.001518931,0.000297029,0.0009133848,0.00004133773,0.001157297,0.0002311149],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008897091,"about_ca_system_score_gemma":0.000310399,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009379314,"about_ca_topic_score_gemma":0.00179089,"domain_scores_codex":[0.9947281,0.0002496721,0.001508933,0.001368044,0.000845535,0.001299732],"domain_scores_gemma":[0.9969791,0.0006292812,0.0006246595,0.00115941,0.0001633914,0.0004441898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001232979,0.0009132629,0.0001211977,0.0004649233,0.0004434955,0.00001248337,0.0005344391,0.000547361,0.8279786,0.00006747367,0.00009203939,0.1687015],"study_design_scores_gemma":[0.001911833,0.0001632003,0.005502122,0.0002208721,0.0008614344,0.000099349,0.0004707761,0.001072278,0.986503,0.0002518133,0.001991216,0.0009520865],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.987624,0.0009762097,0.008410396,0.0004483594,0.000217014,0.0006549931,0.0003252951,0.000309899,0.001033839],"genre_scores_gemma":[0.9949366,0.003338277,0.0001196117,0.0001135332,0.0002841605,0.0004782716,0.0004652975,0.0001919398,0.0000722687],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1677494,"threshold_uncertainty_score":0.9991853,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0074582576644347,"score_gpt":0.2200940409466556,"score_spread":0.2126357832822209,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}