{"id":"W1969450750","doi":"10.1021/om100321n","title":"Synthesis and Structural Characterization of the First Copper(I) Complexes with Bis(imino)-N-heterocyclic Carbene NCN Pincer Ligands","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; York University","funders":"National Comprehensive Cancer Network","keywords":"Chemistry; Carbene; Deprotonation; Bimetallic strip; Pincer movement; Ligand (biochemistry); Copper; Medicinal chemistry; Metal; Transition metal carbene complex; Polymer chemistry; Stereochemistry; Organic chemistry; Catalysis; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006199122,0.0003837307,0.000467001,0.00004551078,0.0002726398,0.00008405358,0.0006010766,0.0002721218,0.001668628],"category_scores_gemma":[0.00009695649,0.0002707385,0.0001140104,0.0002802101,0.0005062416,0.0001646441,0.0003255732,0.0004292974,0.000003954201],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000574459,"about_ca_system_score_gemma":0.00006453383,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003566101,"about_ca_topic_score_gemma":0.0001091664,"domain_scores_codex":[0.9983348,0.00000801297,0.0004537003,0.0004788807,0.0003753956,0.0003492004],"domain_scores_gemma":[0.9983951,0.0001062729,0.0003580362,0.0009095574,0.00009770448,0.0001333325],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002938162,0.00003795101,0.02590119,0.0002224564,0.0001035874,0.000001561377,0.0002135631,5.79689e-7,0.972776,0.0001141826,0.00002138838,0.0005781901],"study_design_scores_gemma":[0.0004304731,0.00001645356,0.02939528,0.00007453198,0.0001530455,0.000134908,0.0000857229,0.00003407856,0.9662728,0.00003594794,0.003018829,0.0003479784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972391,0.00005876358,0.000008463592,0.0003343501,0.00021665,0.0001024029,0.0001493021,0.00007345341,0.001817554],"genre_scores_gemma":[0.9988155,0.00009763658,0.00008226852,0.00009084082,0.0002480841,0.00001563909,0.00004985792,0.00008189683,0.000518312],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006503223,"threshold_uncertainty_score":0.9999745,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005998245379932641,"score_gpt":0.1959722785914994,"score_spread":0.1899740332115667,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}