{"id":"W1969555457","doi":"10.1021/jp056113s","title":"An EPR Study of the C−O Bond Activation of 1,2-Epoxybutane by Ground-State Al Atoms","year":2006,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"","keywords":"Electron paramagnetic resonance; Hyperfine structure; Chemistry; Isotopomers; Matrix isolation; Crystallography; Ground state; Paramagnetism; Nuclear magnetic resonance; Molecule; Atomic physics; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001042087,0.0001607008,0.00009821191,0.00009794573,0.0001366165,0.0001263854,0.0001987773,0.0002343125,0.001114926],"category_scores_gemma":[0.0001200388,0.00006821322,0.00008485335,0.00007814434,0.0002090487,0.0001736216,0.0001039036,0.0002797201,0.0001446924],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009565222,"about_ca_system_score_gemma":0.00005415777,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002090794,"about_ca_topic_score_gemma":0.0001735698,"domain_scores_codex":[0.9999548,0.00001009482,0.000001043212,0.000009293703,0.00001138946,0.00001325047],"domain_scores_gemma":[0.9999487,0.00001567855,0.000009917568,0.000004988717,0.00001248128,0.000008217899],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001070908,0.00003080811,0.0002619204,0.00002587301,0.00000462972,0.00006119071,0.00004541335,0.00005697631,0.9979746,0.0001648473,0.00003043487,0.001236274],"study_design_scores_gemma":[0.00002085656,0.0003867545,0.002937196,0.000003379791,0.000007275999,0.0001433906,0.00005332287,0.001252325,0.9939829,0.00007606606,0.00113264,0.000004012399],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980536,0.0002026861,0.0009007392,0.00002116019,0.000005155598,0.000005976955,0.0000191593,0.00001046148,0.0007810898],"genre_scores_gemma":[0.9980612,0.0001160336,0.0006711967,0.00001310575,0.000004491294,0.000003950462,0.00006034134,0.000004813885,0.001064724],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001114926,"threshold_uncertainty_score":0.00372982,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005171942325447658,"score_gpt":0.2474330263807038,"score_spread":0.2422610840552562,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}