{"id":"W1969613977","doi":"10.1080/00397911.2011.626140","title":"Ruthenium-Catalyzed Nucleophilic Ring-Opening Reactions of 7-Oxabenzonorbornadienes with Methanol","year":2013,"lang":"en","type":"article","venue":"Synthetic Communications","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Ruthenium; Catalysis; Methanol; Ring (chemistry); Nucleophile; Medicinal chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001728797,0.0002315758,0.0003339809,0.0001737013,0.0004182814,0.0000615509,0.001258875,0.000106466,0.001879619],"category_scores_gemma":[0.0002581051,0.000214871,0.0001418043,0.0004230448,0.0005626897,0.0003020165,0.0004044425,0.000391023,0.0004522206],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001289146,"about_ca_system_score_gemma":0.0001291801,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003060357,"about_ca_topic_score_gemma":0.0004541236,"domain_scores_codex":[0.9985527,0.00004990258,0.0005503048,0.0003013649,0.0002286223,0.000317046],"domain_scores_gemma":[0.9943445,0.0008363551,0.0003610936,0.004027299,0.0002776905,0.0001530863],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003008628,0.001046692,0.00149726,0.0002211453,0.0007178207,0.000001608909,0.002785657,0.0001039982,0.9413987,0.02447279,0.0002052875,0.02751889],"study_design_scores_gemma":[0.004477276,0.0001680094,0.01048593,0.002778279,0.002426676,0.001154691,0.02507976,0.01662866,0.6956361,0.01373471,0.2238791,0.003550838],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7677237,0.0006476753,0.0007237035,0.003531319,0.00006722817,0.0004798208,0.00008943728,0.0003938187,0.2263433],"genre_scores_gemma":[0.9915609,0.0001581557,0.006135366,0.00001038306,0.00002686323,0.000369739,0.00007519869,0.00005995249,0.001603464],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2457627,"threshold_uncertainty_score":0.9990328,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0200530447250706,"score_gpt":0.246576714558996,"score_spread":0.2265236698339254,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}