{"id":"W1969815175","doi":"10.1139/v06-167","title":"The absolute configuration of a nitroxide spin labeled derivative of podophyllotoxin determined by the crystal structure","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Plant-derived Lignans Synthesis and Bioactivity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Podophyllotoxin; Chemistry; Nitroxide mediated radical polymerization; Nitroxyl; Derivative (finance); Absolute configuration; Crystal structure; Molecule; Stereochemistry; Crystal (programming language); Crystallography; Photochemistry; Organic chemistry; Polymer","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006867735,0.0001038792,0.0001497284,0.00009744491,0.0002386818,0.0004103262,0.0002794978,0.0002263642,0.001325635],"category_scores_gemma":[0.0002297131,0.0001015436,0.00005590006,0.0002526021,0.0003891781,0.0001630571,0.0000935464,0.0009349902,0.0001949923],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005599153,"about_ca_system_score_gemma":0.0004961144,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002117962,"about_ca_topic_score_gemma":0.002228253,"domain_scores_codex":[0.9999603,0.000003777681,0.000001919624,0.00001108974,0.00001630094,0.00000661006],"domain_scores_gemma":[0.99985,0.00003505544,0.00004093233,0.00001433997,0.00003220085,0.00002753765],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008550975,0.00005846778,0.001016912,0.0000540801,0.000005853269,0.0001675224,0.00006858901,0.0005679668,0.9906422,0.002121801,0.0004205818,0.004790414],"study_design_scores_gemma":[0.00006426399,0.0002996454,0.006825026,0.00001312208,0.00001906413,0.0003498086,0.0001473619,0.004223269,0.9784095,0.000776464,0.008858382,0.00001409733],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909123,0.0004848576,0.003538359,0.0002021937,0.00007369651,0.00001917833,0.0004479587,0.00004639053,0.004275072],"genre_scores_gemma":[0.9907151,0.0005598819,0.004699308,0.00005291003,0.00001364874,0.00001816466,0.0009468821,0.00001720053,0.002976757],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002117962,"threshold_uncertainty_score":0.004434705,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004037413021866857,"score_gpt":0.188419839844621,"score_spread":0.1843824268227541,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}