{"id":"W1969837635","doi":"10.1021/ja012252l","title":"Exploring the Hydroxylation−Dehydrogenation Connection:  Novel Catalytic Activity of Castor Stearoyl-ACP Δ<sup>9</sup> Desaturase","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Lipid metabolism and biosynthesis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; Health Canada","funders":"","keywords":"Chemistry; Hydroxylation; Dehydrogenation; Substrate (aquarium); Catalysis; Stereochemistry; Branching (polymer chemistry); Double bond; Oxidative phosphorylation; Enzyme; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000140461,0.0003089855,0.0001549249,0.0000847901,0.00009784417,0.0002624347,0.0001485845,0.0001625836,0.0003731268],"category_scores_gemma":[0.0001007596,0.00009201837,0.0001555062,0.00008148669,0.0001815934,0.0001652993,0.0001152085,0.0002958787,0.0001476843],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002837327,"about_ca_system_score_gemma":0.0001973364,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008683495,"about_ca_topic_score_gemma":0.001625742,"domain_scores_codex":[0.999944,0.000007998027,0.000003748757,0.00001384727,0.00001479395,0.00001569957],"domain_scores_gemma":[0.9999392,0.00001288844,0.00001441583,0.000008897963,0.000009737986,0.00001481273],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006147561,0.000009174733,0.0002738164,0.00001230004,0.000002473732,0.00004203049,0.000008536261,0.00005876683,0.998004,0.00009264526,0.000004673846,0.001429924],"study_design_scores_gemma":[0.000002381602,0.00005109305,0.0006409216,6.394785e-7,0.000003785038,0.00006841323,0.000005292757,0.0002262608,0.9987006,0.00002516029,0.0002741225,0.000001267214],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951882,0.0005041021,0.003388299,0.00004425057,0.000007232035,0.00001028768,0.00006747716,0.00002484598,0.0007653029],"genre_scores_gemma":[0.9967078,0.0003154017,0.002223775,0.00001220974,0.000003169165,0.000003770406,0.0001316824,0.000007028129,0.0005951709],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008683495,"threshold_uncertainty_score":0.002058625,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03485648648517436,"score_gpt":0.2330979332435583,"score_spread":0.198241446758384,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}