{"id":"W1969848498","doi":"10.1021/ol702414e","title":"Cycloadditions of Aromatic Azomethine Imines with 1,1-Cyclopropane Diesters","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":206,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cyclopropane; Cycloaddition; Tricyclic; Catalysis; Aldimine; Organic chemistry; Combinatorial chemistry; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004422085,0.0002526085,0.0003303285,0.000115792,0.0001480846,0.000011866,0.0002362612,0.00007980337,0.001691881],"category_scores_gemma":[0.0000573753,0.0002131988,0.00008413434,0.000323592,0.0002099411,0.0001583633,0.0000484631,0.0002250822,0.00009546576],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001280311,"about_ca_system_score_gemma":0.00006409125,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004824364,"about_ca_topic_score_gemma":0.00001542807,"domain_scores_codex":[0.9986171,0.00001678701,0.0003461931,0.0003182134,0.0004026387,0.0002990333],"domain_scores_gemma":[0.9989725,0.0000960693,0.000237009,0.0005394301,0.00005109109,0.0001038638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002602387,0.00006876678,0.0007415251,0.0001644123,0.00007574921,0.00009295891,0.001149489,0.00001210055,0.9966304,0.00001145123,0.0007262796,0.0003007836],"study_design_scores_gemma":[0.0009057301,0.00005224285,0.001455672,0.0001186734,0.00009388696,0.0008809186,0.0007366169,0.00001009575,0.994217,0.00002612239,0.001162426,0.0003406274],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961264,0.00004903139,0.0006931783,0.001362337,0.00008898278,0.00009749256,0.00002216377,0.0002016164,0.001358856],"genre_scores_gemma":[0.9956973,0.00004934967,0.003217837,0.0003875448,0.0001308372,0.00002796309,0.00007237501,0.00007172869,0.000345033],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002524659,"threshold_uncertainty_score":0.9992207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01104866680395154,"score_gpt":0.1963253431635868,"score_spread":0.1852766763596353,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}