{"id":"W1970120740","doi":"10.1021/ol701447q","title":"Removal, Recovery, and Recycling of Triarylphosphonium-Supported Tin Reagents for Various Organic Transformations","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Tin; Reagent; Chemistry; Phosphonium; Stille reaction; Catalysis; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003543918,0.0005057033,0.0002948581,0.0004878746,0.0002024786,0.0003884355,0.0007146359,0.0003927958,0.0007481998],"category_scores_gemma":[0.0003943171,0.0002513914,0.0002749609,0.0003983449,0.0002032963,0.0003464243,0.0002540953,0.000439944,0.000437767],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002670975,"about_ca_system_score_gemma":0.0003160326,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004316924,"about_ca_topic_score_gemma":0.001036475,"domain_scores_codex":[0.9998108,0.00002151244,0.00002460153,0.0000301434,0.00006700182,0.00004606289],"domain_scores_gemma":[0.9999055,0.0000167235,0.00002191433,0.00002105475,0.0000207115,0.00001408596],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007416515,0.00004021601,0.0001257901,0.00007674793,0.00001034685,0.0001388227,0.00002105414,0.0001830022,0.9917602,0.0002387541,0.00004139601,0.007289587],"study_design_scores_gemma":[0.000003871085,0.00004908994,0.00009422612,0.000001648296,0.000008816656,0.00007513056,0.000003591546,0.0003076812,0.998992,0.00001611914,0.0004457431,0.000002028682],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9603941,0.003693215,0.03058846,0.00009179598,0.00005809449,0.0001120588,0.0002404778,0.0002892209,0.00453274],"genre_scores_gemma":[0.9796754,0.001915504,0.01411488,0.00003733459,0.000009060001,0.00003521554,0.0004109858,0.00005410807,0.003747417],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007481998,"threshold_uncertainty_score":0.002502918,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01145460729436384,"score_gpt":0.2505134280816606,"score_spread":0.2390588207872968,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}