{"id":"W1970120740","doi":"10.1021/ol701447q","title":"Removal, Recovery, and Recycling of Triarylphosphonium-Supported Tin Reagents for Various Organic Transformations","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Tin; Reagent; Chemistry; Phosphonium; Stille reaction; Catalysis; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005319796,0.0002009535,0.0002948593,0.0001079474,0.0001915435,0.00005015174,0.0001828539,0.0001713204,0.000725186],"category_scores_gemma":[0.0003460135,0.0002226448,0.0001286633,0.0002982703,0.00009301895,0.000179229,0.00003115145,0.0002369112,0.00002151681],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002488661,"about_ca_system_score_gemma":0.0001102236,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001036449,"about_ca_topic_score_gemma":0.00009561177,"domain_scores_codex":[0.9984039,0.000001162521,0.0006860521,0.0003259274,0.0002053563,0.0003775861],"domain_scores_gemma":[0.9987193,0.0003933312,0.0002671968,0.0004210635,0.00008826458,0.0001108482],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001148013,0.00006776612,0.0002375414,0.0001175181,0.0001008642,0.00001383769,0.000623851,0.000003453132,0.9948838,0.0000123981,0.001400279,0.002423925],"study_design_scores_gemma":[0.001734343,0.0000221558,0.0003493715,0.00006130511,0.0001695034,0.0002450348,0.0002169174,0.0001169039,0.9942851,0.00008275777,0.002476248,0.0002403391],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865221,0.00006370919,0.01141337,0.001097248,0.0002696811,0.0002322496,0.00008074897,0.0001257982,0.0001950405],"genre_scores_gemma":[0.9980814,0.00006744191,0.0008235708,0.0002983572,0.0001282034,0.000008552028,0.0001728981,0.00007136488,0.0003481584],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0115593,"threshold_uncertainty_score":0.9079192,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01145460729436384,"score_gpt":0.2505134280816606,"score_spread":0.2390588207872968,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}