{"id":"W1970153747","doi":"10.1039/b912093a","title":"Intramolecular cross-coupling of gem-dibromoolefins: a mild approach to 2-bromo benzofused heterocycles","year":2009,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":127,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Intramolecular force; Chemistry; Coupling (piping); Combinatorial chemistry; Medicinal chemistry; Computational chemistry; Stereochemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002160691,0.0005026667,0.000276386,0.0002112308,0.0001882576,0.0001744425,0.000374824,0.0002948379,0.001560122],"category_scores_gemma":[0.0001370096,0.000197833,0.000207262,0.000181438,0.0002032434,0.0002198544,0.0003724353,0.0004809943,0.0004284185],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003453796,"about_ca_system_score_gemma":0.0002360262,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006538738,"about_ca_topic_score_gemma":0.00179387,"domain_scores_codex":[0.9998356,0.00002803245,0.00001033968,0.00003247216,0.00003368382,0.00005979019],"domain_scores_gemma":[0.9999382,0.000009737048,0.00001766191,0.000009198231,0.000007141878,0.00001802834],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005655069,0.00002246368,0.00005392226,0.00005339788,0.000008273316,0.0001207167,0.00004119144,0.0001817074,0.9958948,0.0005280838,0.00008432966,0.002954643],"study_design_scores_gemma":[0.00001393007,0.0001775376,0.0005432846,0.00000422001,0.000007881191,0.0001811018,0.000009611548,0.0001754126,0.9951276,0.00005810852,0.003694497,0.000006917724],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9674276,0.003190535,0.02195945,0.000164715,0.00005111605,0.0000757381,0.0003072109,0.0002705941,0.006553018],"genre_scores_gemma":[0.9887449,0.001692962,0.005222233,0.00005831986,0.00001584919,0.00004627299,0.0002174659,0.00003842903,0.003963475],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001560122,"threshold_uncertainty_score":0.005219102,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03743545398438528,"score_gpt":0.3222020839952804,"score_spread":0.2847666300108951,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}