{"id":"W1970168481","doi":"10.1039/b404740k","title":"Cu(<scp>ii</scp>)-Mediated decomposition of phosphorothionate PS pesticides. Billion-fold acceleration of the methanolysis of fenitrothion promoted by a simple Cu(<scp>ii</scp>)–ligand system","year":2004,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Methoxide; Dimer; Reaction rate constant; Medicinal chemistry; Ligand (biochemistry); Catalysis; Stereochemistry; Kinetics; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001278267,0.0004531093,0.0002849126,0.0001086289,0.00008490613,0.0001828829,0.0002798113,0.0003810114,0.001020025],"category_scores_gemma":[0.0002691251,0.0001259595,0.0001788782,0.0001347944,0.0001904368,0.0002492781,0.0002149261,0.0003497914,0.0003037557],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003935244,"about_ca_system_score_gemma":0.0002356534,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001789302,"about_ca_topic_score_gemma":0.002495696,"domain_scores_codex":[0.9998707,0.00001959074,0.000007930756,0.00003977749,0.00002834474,0.00003360043],"domain_scores_gemma":[0.9999194,0.0000181171,0.00002393836,0.000006130536,0.00001700283,0.00001528083],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001178968,0.000008192583,0.00007490881,0.00007072844,0.000007905366,0.00002299951,0.00002183987,0.0001303836,0.9982267,0.00003783753,0.00003907747,0.001241582],"study_design_scores_gemma":[0.000004359812,0.0001333694,0.0004095768,0.00000326434,0.000004885972,0.00002660781,0.000008305075,0.0003811603,0.9985905,0.000008781432,0.0004259874,0.000003107787],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940944,0.000796159,0.00302421,0.00005018236,0.00001602599,0.00004243657,0.0003344373,0.0001651262,0.001477068],"genre_scores_gemma":[0.9956602,0.00046091,0.002066465,0.00001704113,0.000003997416,0.00003088797,0.0002462797,0.00002355806,0.001490483],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001789302,"threshold_uncertainty_score":0.003557861,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01096589160604969,"score_gpt":0.2285125130721479,"score_spread":0.2175466214660982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}