{"id":"W1970171193","doi":"10.1021/ja9911869","title":"Selected Radical Removal from Proton-Bound Dimers. A Strategy for Studying Solvated Distonic Ions","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Catalysis; Photochemistry; Deuterium; Metastability; Ion; Proton; Molecule; Methanol; Radical ion; Methyl radical; Proton affinity; Mass spectrometry; Radical; Organic chemistry; Protonation; Atomic physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001669882,0.0002982785,0.00019446,0.0001382948,0.0001455627,0.0001903411,0.0004328427,0.0002944547,0.0011027],"category_scores_gemma":[0.000212293,0.0001358183,0.0001374549,0.0001072211,0.0002010157,0.0004193264,0.0003011511,0.0005303171,0.0002739122],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001832939,"about_ca_system_score_gemma":0.0001151468,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001443466,"about_ca_topic_score_gemma":0.0002718976,"domain_scores_codex":[0.9999062,0.00001117545,0.000002836837,0.00003023501,0.00002530293,0.00002429009],"domain_scores_gemma":[0.9999199,0.00001555271,0.00002535681,0.00001244424,0.00001030484,0.00001642822],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007172009,0.0000123928,0.00008700688,0.00002626024,0.00000518787,0.00003168828,0.00002431006,0.00005208173,0.9980795,0.0001270097,0.00003322487,0.001449443],"study_design_scores_gemma":[0.00001119093,0.00009892321,0.0003190525,0.000001013294,0.000003517838,0.00007235603,0.00001243116,0.0003757366,0.998362,0.00006243384,0.0006786297,0.000002713303],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851275,0.0008648184,0.01254509,0.00006459329,0.00002205573,0.00004250481,0.0001039979,0.00006356421,0.001165928],"genre_scores_gemma":[0.9917778,0.0004187519,0.005035558,0.00006543694,0.000008432392,0.00003432319,0.0001814965,0.00002569198,0.002452594],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0011027,"threshold_uncertainty_score":0.003688872,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01605502913084779,"score_gpt":0.2826831962952431,"score_spread":0.2666281671643954,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}