{"id":"W1970193874","doi":"10.1139/v00-043","title":"Synthesis of 8-<i>epi</i>-castanospermine and 6,7,8-tri-<i>epi</i>-castanospermine","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Phytochemical Studies and Bioactivities","field":"Biochemistry, Genetics and Molecular Biology","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Castanospermine; Chemistry; Stereochemistry; Organic chemistry; Enzyme","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001430775,0.0004780951,0.0003927742,0.0001968816,0.0002387558,0.0002062269,0.0002794965,0.0003104397,0.003064739],"category_scores_gemma":[0.0001884654,0.0001806119,0.0002764986,0.0002409769,0.0001360322,0.0001951225,0.0001650892,0.0006584533,0.001280925],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002411884,"about_ca_system_score_gemma":0.0005261678,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008073535,"about_ca_topic_score_gemma":0.001940877,"domain_scores_codex":[0.9999117,0.00001427035,0.000008549496,0.00001971578,0.00002243329,0.00002334291],"domain_scores_gemma":[0.9998919,0.00001527968,0.00001955665,0.00001625322,0.00002289931,0.00003412072],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000746711,0.00002270528,0.00004537695,0.0001112407,0.000006980802,0.0001910237,0.00002906319,0.00017919,0.9940555,0.0003367326,0.00007811394,0.00486942],"study_design_scores_gemma":[0.0000249827,0.0002588725,0.0005336886,0.000008926046,0.00001633784,0.000296316,0.00002033983,0.0002607118,0.9894242,0.0001002189,0.009045448,0.000009876003],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.901682,0.008807398,0.0446128,0.0003612569,0.0003787088,0.0005673783,0.003536176,0.0004657571,0.03958854],"genre_scores_gemma":[0.9380956,0.004710082,0.03417253,0.0001410945,0.00004792365,0.0001342745,0.00222977,0.00008458788,0.02038413],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003064739,"threshold_uncertainty_score":0.01025259,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005276542164327387,"score_gpt":0.1906609272721039,"score_spread":0.1853843851077765,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}