{"id":"W1970200636","doi":"10.1021/jo050077b","title":"Sulfur-Based Protecting Groups for Pyrroles and the Facile Deprotection of 2-(2,4-Dinitrobenzene)sulfinyl and Sulfonyl Pyrroles","year":2005,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis and Characterization of Pyrroles","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Sulfonyl; Chemistry; Sulfur; Polar effect; Benzene; Medicinal chemistry; Proton NMR; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001123771,0.0002055399,0.0003685568,0.00002724992,0.0002888387,0.0000535254,0.0002979667,0.0001412087,0.0003397541],"category_scores_gemma":[0.0006518292,0.0001246703,0.000124026,0.00008631897,0.0002445135,0.0001123856,0.00005998718,0.0003598979,5.535707e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004156196,"about_ca_system_score_gemma":0.00008163787,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000577259,"about_ca_topic_score_gemma":0.000006691288,"domain_scores_codex":[0.9987147,0.00005175994,0.0006253858,0.0001516863,0.0002639654,0.0001925193],"domain_scores_gemma":[0.9979549,0.0006049925,0.0009079303,0.0002536986,0.0002076319,0.0000708588],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005972627,0.00005179879,0.0002405514,0.0002765724,0.00007543222,4.296737e-7,0.0004855504,0.00003368723,0.9921935,0.000008485411,0.00002318932,0.00601357],"study_design_scores_gemma":[0.002390508,0.00002865846,0.0002563578,0.0001783575,0.0001564334,0.000157463,0.001877617,0.0004986383,0.9934751,0.0001624871,0.0006810324,0.0001373057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943834,0.001111659,0.002151473,0.00200923,0.00002303131,0.000143208,0.00002108583,0.00002024576,0.0001366935],"genre_scores_gemma":[0.9987202,0.0002093166,0.0003969132,0.00006062579,0.0004519842,0.00001273699,0.000003232754,0.00003356593,0.0001114371],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005876264,"threshold_uncertainty_score":0.5083908,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008572968772332157,"score_gpt":0.2006427762348068,"score_spread":0.1920698074624746,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}