{"id":"W1970221734","doi":"10.1016/s0022-328x(01)01395-x","title":"Raman and infrared spectra and pressure tuning Raman and infrared spectra of multinuclear metal carbyne complexes","year":2002,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"University of Hong Kong","keywords":"Carbyne; Raman spectroscopy; Chemistry; Infrared; Infrared spectroscopy; Spectral line; Metal; Analytical Chemistry (journal); Photochemistry; Optics; Organic chemistry; Astronomy; Carbene; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001570705,0.0002444574,0.000192931,0.0002997343,0.0002863519,0.000277486,0.0006725672,0.0003810804,0.002780475],"category_scores_gemma":[0.0003510184,0.0001833484,0.0001346975,0.0002372891,0.00031636,0.000284598,0.0002438879,0.0003637735,0.0002225379],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002807742,"about_ca_system_score_gemma":0.0001115933,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001391909,"about_ca_topic_score_gemma":0.001740202,"domain_scores_codex":[0.9997955,0.00001788566,0.00000906631,0.0000449048,0.00009246331,0.00004017535],"domain_scores_gemma":[0.9998366,0.00006865591,0.00003081292,0.00001870453,0.00002636267,0.00001886583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002974168,0.00001494075,0.0002909952,0.00003525365,0.00000846445,0.00007621,0.00008670565,0.0001411641,0.9970572,0.0003163303,0.0001414643,0.001533904],"study_design_scores_gemma":[0.00002042135,0.000143448,0.005975361,0.000006042081,0.00001413559,0.0002485886,0.00007246934,0.00147466,0.9904385,0.00008634679,0.00150541,0.00001450622],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944531,0.0006768502,0.0007307476,0.00008945788,0.00001256499,0.000006940013,0.0001319445,0.00003597928,0.003862423],"genre_scores_gemma":[0.9965935,0.0001970167,0.0006715689,0.00002652031,0.000005335863,0.000006314704,0.000169369,0.00001925313,0.002311128],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002780475,"threshold_uncertainty_score":0.009301603,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01309709171811707,"score_gpt":0.2028159977143556,"score_spread":0.1897189059962385,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}