{"id":"W1970243200","doi":"10.1039/c2pp25167a","title":"Studies of the solvatochromic emission properties of N-aroylurea derivatives II: influence of hydrogen-bonding interactions","year":2012,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Victoria","funders":"Deutsche Forschungsgemeinschaft","keywords":"Solvatochromism; Bathochromic shift; Intramolecular force; Conformational isomerism; Chemistry; Excited state; Photochemistry; Hydrogen bond; Substituent; Emission spectrum; Solvation; Stokes shift; Crystallography; Solvent; Molecule; Fluorescence; Stereochemistry; Spectral line; Luminescence; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.0003533391,0.0002562074,0.0005615677,0.00003216946,0.0003630827,0.000005560645,0.0007633145,0.000119803,0.0001155328],"category_scores_gemma":[0.0009125767,0.0001359868,0.000230098,0.0004639091,0.003400085,0.0001861682,0.0004308268,0.0002789884,5.749069e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005126922,"about_ca_system_score_gemma":0.00006681045,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006125504,"about_ca_topic_score_gemma":0.000001669895,"domain_scores_codex":[0.9981675,0.00004572457,0.000665299,0.0003268723,0.0003177593,0.0004768255],"domain_scores_gemma":[0.9988353,0.000295286,0.0003624139,0.0002625905,0.000156644,0.00008777851],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007532472,0.000297763,0.01756651,0.0002272953,0.00009352121,8.352881e-8,0.001388185,0.00002082958,0.9801886,0.00008864453,0.00003184901,0.00002140634],"study_design_scores_gemma":[0.0001670037,0.00008105546,0.00056213,0.0005188956,0.00003540103,0.000008657045,0.001417054,0.00002278408,0.9965161,0.0004108588,0.00009112257,0.0001689039],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961278,0.002119522,0.000001223029,0.00007817955,0.00003251087,0.0002330032,0.00002214379,0.00002794424,0.001357601],"genre_scores_gemma":[0.9995416,0.0001167438,0.00007910339,0.00002290227,0.00003484582,0.000129994,0.000001767988,0.000005633872,0.00006736338],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01700438,"threshold_uncertainty_score":0.9993121,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06549699723191027,"score_gpt":0.3165981136566545,"score_spread":0.2511011164247442,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}