{"id":"W1970309501","doi":"10.1021/ja300587z","title":"Synthesis, Reactivity, and Computational Analysis of Halophosphines Supported by Dianionic Guanidinate Ligands","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Reactivity (psychology); Phosphine; Carbodiimide; Ring (chemistry); Medicinal chemistry; Halide; Acceptor; Metal; Stereochemistry; Polymer chemistry; Computational chemistry; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002991776,0.0005332294,0.0005982359,0.0004698428,0.0004055421,0.0005883872,0.0008785835,0.0005856557,0.002386912],"category_scores_gemma":[0.0005147598,0.000245612,0.0003285755,0.0003843159,0.0002844661,0.0003107337,0.0002935603,0.0005039611,0.000202767],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007532993,"about_ca_system_score_gemma":0.0005360405,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003742948,"about_ca_topic_score_gemma":0.005065287,"domain_scores_codex":[0.9999276,0.00001574093,0.000003921873,0.00001038772,0.00001829126,0.00002409035],"domain_scores_gemma":[0.9998073,0.0001229437,0.00001955804,0.0000108427,0.00002404265,0.00001532502],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007721643,0.0002844092,0.005375037,0.0008340332,0.0001257646,0.0007142009,0.0001088102,0.9495135,0.0217852,0.009286921,0.001577352,0.009622702],"study_design_scores_gemma":[0.000169027,0.0004369266,0.001123973,0.00002024968,0.00004965307,0.00006644442,0.00009875953,0.9843478,0.01087591,0.00132764,0.001467733,0.00001584671],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916546,0.0003074369,0.0009347703,0.0001133177,0.00001045374,0.00002019196,0.0005656058,0.00007344387,0.006320187],"genre_scores_gemma":[0.9928536,0.0003484725,0.005134223,0.00005267516,0.000006894561,0.00005040267,0.0009190619,0.00003434156,0.0006004384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003742948,"threshold_uncertainty_score":0.007984996,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01045413801953301,"score_gpt":0.2727952234746371,"score_spread":0.2623410854551041,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}