{"id":"W1970328519","doi":"10.1021/ic100219j","title":"Synthesis of Gold Phosphido Complexes Derived from Bis(secondary) Phosphines. Structure of Tetrameric [Au(MesP(CH<sub>2</sub>)<sub>3</sub>PMes)Au]<sub>4</sub>","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Nuclear magnetic resonance spectroscopy; Tetrahydrothiophene; Crystallography; NMR spectra database; Spectroscopy; Aqueous solution; Stereochemistry; Spectral line; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0002829049,0.001624643,0.00262002,0.0001960492,0.000327854,0.0001552657,0.00233929,0.001275874,0.01060817],"category_scores_gemma":[0.001105707,0.001701534,0.001163342,0.001381055,0.001266617,0.0003488364,0.0008649209,0.001793868,0.00008879865],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004873644,"about_ca_system_score_gemma":0.001265495,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005780411,"about_ca_topic_score_gemma":0.0006409968,"domain_scores_codex":[0.9928506,0.00006305566,0.002282829,0.00201661,0.001333074,0.001453854],"domain_scores_gemma":[0.9926089,0.00104875,0.001885103,0.00325351,0.0004715302,0.0007321836],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001383551,0.0005788648,0.004359933,0.001184193,0.001214307,0.00002762696,0.0003835275,0.000004735718,0.9523488,0.00001130901,0.0004552803,0.03929304],"study_design_scores_gemma":[0.0011869,0.00002754058,0.01331955,0.0002967962,0.001009318,0.00008098544,0.0006261517,0.00005227352,0.9808398,0.0002642085,0.0006551403,0.001641256],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932169,0.0009081009,0.00002148371,0.0001690112,0.0003799894,0.000255993,0.002854541,0.0003064451,0.001887477],"genre_scores_gemma":[0.9971579,0.0003663662,0.0002199823,0.0000822915,0.0009554606,0.00005090669,0.0007333214,0.0003669438,0.00006680547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03765178,"threshold_uncertainty_score":0.9996501,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00507824992961162,"score_gpt":0.1861343052981947,"score_spread":0.181056055368583,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}