{"id":"W1970357365","doi":"10.1021/ic100760t","title":"Preparation and Characterization of (CNSSS)<sub>2</sub>(A)<sub>2</sub>(A = AsF<sub>6</sub><sup>−</sup>, SbF<sub>6</sub><sup>−</sup>, Sb<sub>2</sub>F<sub>11</sub><sup>−</sup>) Containing the O<sub>2</sub>-like 5,5′-Bis(1,2,3,4-trithiazolium) Dication: The Second Example of a Simple Nonsterically Hindered Main-Group Diradical That Retains Its Paramagnetism in the Solid State","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of New Brunswick; Dalhousie University","funders":"","keywords":"Chemistry; Crystallography; Diradical; Diamagnetism; Delocalized electron; Intramolecular force; Crystal structure; Stoichiometry; Singlet state; Computational chemistry; Stereochemistry; Atomic physics; Physical chemistry; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.004989501,0.004651493,0.004546033,0.0008609038,0.002994295,0.001807035,0.005547497,0.004841008,0.0002916547],"category_scores_gemma":[0.001525804,0.004109542,0.00178672,0.00410294,0.003606296,0.002390986,0.002601498,0.008642101,0.0002350975],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001720606,"about_ca_system_score_gemma":0.00296242,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001692112,"about_ca_topic_score_gemma":0.0006613184,"domain_scores_codex":[0.9753876,0.001777264,0.007241414,0.005566917,0.004859804,0.005167003],"domain_scores_gemma":[0.9806854,0.003596259,0.005259932,0.00681383,0.001769577,0.001874961],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001570945,0.001866686,0.002042934,0.001884467,0.001459815,0.0003294932,0.01179854,0.000977468,0.9675927,0.0002062324,0.002401234,0.007869544],"study_design_scores_gemma":[0.008163506,0.0006923833,0.003486373,0.001127891,0.001432123,0.002138386,0.004364531,0.01690849,0.9547489,0.0009891581,0.001727398,0.004220841],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876857,0.001397937,0.0006224334,0.001789495,0.0007685788,0.004062742,0.002019946,0.0009661417,0.0006870229],"genre_scores_gemma":[0.9850911,0.004167858,0.00008448298,0.00147348,0.002230689,0.001155723,0.004580018,0.001139652,0.00007694723],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01593102,"threshold_uncertainty_score":0.999833,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009494969911740689,"score_gpt":0.2151787004442946,"score_spread":0.2056837305325539,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}