{"id":"W1970417958","doi":"10.1139/v05-249","title":"Formation and X-ray structure of the hostguest adduct [Pd<sub>3</sub>(dppm)<sub>3</sub>(CO)(NO<sub>3</sub>)]<sup>+</sup> and the mechanism of its electrochemical reduction","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Conseil régional de Bourgogne-Franche-Comté; Centre National de la Recherche Scientifique","keywords":"Chemistry; Adduct; Electrochemistry; Palladium; Crystallography; Reaction rate constant; Cluster (spacecraft); Stereochemistry; Kinetics; Physical chemistry; Electrode; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003076661,0.0004370626,0.0006804413,0.0001019418,0.0003382382,0.00009098497,0.0005824884,0.0004589165,0.00003675621],"category_scores_gemma":[0.0002408349,0.0003271368,0.0003678162,0.0004657944,0.0005575058,0.0002457653,0.00005408176,0.001046964,0.000002329689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002739041,"about_ca_system_score_gemma":0.000574405,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008377339,"about_ca_topic_score_gemma":0.0001702512,"domain_scores_codex":[0.9972687,0.00005679451,0.001156097,0.0004002713,0.0005339792,0.0005841986],"domain_scores_gemma":[0.9971218,0.0001282072,0.001173648,0.0005263417,0.0005972877,0.0004527512],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007505192,0.0000379495,0.00005836829,0.0003137487,0.0001463651,0.000002804678,0.0001737738,0.0000531455,0.9966145,0.0002376239,0.001726103,0.0005605957],"study_design_scores_gemma":[0.001028959,0.00002429347,0.00007440353,0.0002286778,0.0003217358,0.0005251485,0.0002168127,0.0005683089,0.9932585,0.003087452,0.0003517267,0.0003139591],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964666,0.001628024,0.00008426834,0.0008737016,0.00003330541,0.0001647403,0.0001437774,0.00001389601,0.0005917264],"genre_scores_gemma":[0.9984323,0.0005560071,0.00004962615,0.00006743885,0.0006823136,0.00001382929,0.0001182535,0.00004676864,0.00003342138],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003355948,"threshold_uncertainty_score":0.999918,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003027475396917794,"score_gpt":0.1727102913179883,"score_spread":0.1696828159210705,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}