{"id":"W1970417958","doi":"10.1139/v05-249","title":"Formation and X-ray structure of the hostguest adduct [Pd3(dppm)3(CO)(NO3)]+ and the mechanism of its electrochemical reduction","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Conseil régional de Bourgogne-Franche-Comté; Centre National de la Recherche Scientifique","keywords":"Chemistry; Adduct; Electrochemistry; Palladium; Crystallography; Reaction rate constant; Cluster (spacecraft); Stereochemistry; Kinetics; Physical chemistry; Electrode; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004669042,0.0001497273,0.00009395362,0.00008477045,0.0001079743,0.0001340432,0.0002950969,0.0003474313,0.00144558],"category_scores_gemma":[0.0002213746,0.0001310073,0.0001040594,0.0001126556,0.0002003314,0.0001658377,0.0001043347,0.0003086022,0.000183332],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002218536,"about_ca_system_score_gemma":0.0001423402,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008674791,"about_ca_topic_score_gemma":0.0007987798,"domain_scores_codex":[0.9999757,0.000002212873,0.000001417598,0.000008278533,0.000008333149,0.00000407728],"domain_scores_gemma":[0.9999317,0.00001689887,0.00002226135,0.000008170606,0.000009543146,0.00001137466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003247999,0.00002513271,0.001594342,0.0001291118,0.00001121074,0.0001344554,0.00006064408,0.001218247,0.9934525,0.000519312,0.0001819386,0.002348116],"study_design_scores_gemma":[0.00001703139,0.0003399849,0.02573943,0.00001453613,0.00002252938,0.0004218834,0.00007170209,0.006090813,0.9628387,0.0003257318,0.00410015,0.00001755362],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963008,0.0004561051,0.001745901,0.0000458108,0.000007768944,0.00001052714,0.0003834908,0.0000489149,0.001000754],"genre_scores_gemma":[0.9956627,0.000244593,0.001554034,0.0000156709,0.000001815685,0.00001047437,0.0008268589,0.00001334138,0.001670619],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00144558,"threshold_uncertainty_score":0.004835963,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003027475396917794,"score_gpt":0.1727102913179883,"score_spread":0.1696828159210705,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}