{"id":"W1970612436","doi":"10.1021/ic100320u","title":"Reactions of α-Diimine Ligands with the in Situ Generated “S(OTf)<sub>2</sub>” Synthon","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Synthon; Diimine; Ligand (biochemistry); Acenaphthene; Reactivity (psychology); Medicinal chemistry; Sulfur; Alkyl; Lability; Stereochemistry; Organic chemistry; Catalysis; Naphthalene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002011721,0.0006094661,0.0002105885,0.0001265979,0.0001178341,0.0001574127,0.0002607357,0.0002151063,0.001790609],"category_scores_gemma":[0.0001985714,0.0001537719,0.0001443386,0.0001228423,0.0002069538,0.0002276358,0.0001676738,0.0002823596,0.0008633219],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000298048,"about_ca_system_score_gemma":0.0001550047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004450884,"about_ca_topic_score_gemma":0.0009540925,"domain_scores_codex":[0.999898,0.00002365075,0.000008032806,0.00002063213,0.00001821473,0.00003148593],"domain_scores_gemma":[0.9999028,0.00002524343,0.00002925769,0.00000909543,0.00001582533,0.00001770503],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001313582,0.00001412163,0.0001276312,0.00007894975,0.000009573608,0.00008902924,0.00004689928,0.0001326987,0.9963143,0.0002622719,0.0001392199,0.002653843],"study_design_scores_gemma":[0.000009234265,0.0001323659,0.0002287401,0.000002404608,0.000004292297,0.0001400497,0.00001579445,0.0002595507,0.9969139,0.00002847486,0.002262072,0.000003126751],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9772421,0.0008674549,0.01063785,0.0001233196,0.00008914281,0.0001395746,0.0001975575,0.0002061514,0.01049685],"genre_scores_gemma":[0.9855746,0.0004631153,0.008154756,0.00005512398,0.00001279736,0.00004213632,0.0002482327,0.00004133977,0.005407947],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001790609,"threshold_uncertainty_score":0.005990207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007363774871614644,"score_gpt":0.1955755909726592,"score_spread":0.1882118161010445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}