{"id":"W1970788398","doi":"10.1016/j.ccr.2011.01.056","title":"Spectroscopic studies of molybdenum and tungsten enzymes","year":2011,"lang":"en","type":"article","venue":"Coordination Chemistry Reviews","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":83,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Molybdenum; Chemistry; Tungsten; Sulfite oxidase; Catalysis; Molybdenum cofactor; Enzyme; Cofactor; Photochemistry; Inorganic chemistry; Biochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000312396,0.0001636731,0.0004592225,0.00002164595,0.0000471446,0.000008534268,0.0001422468,0.00006468044,0.001190902],"category_scores_gemma":[0.0002981234,0.0001321693,0.00008869019,0.0001250996,0.0001040513,0.00009791301,0.00007640441,0.00008085932,0.00003597743],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002662223,"about_ca_system_score_gemma":0.00001276699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003924019,"about_ca_topic_score_gemma":0.000003867046,"domain_scores_codex":[0.9990053,0.00004998729,0.0004527952,0.0002371557,0.0001082383,0.0001465804],"domain_scores_gemma":[0.9992495,0.00002540172,0.0002750823,0.0002985524,0.00009357616,0.00005784356],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002776965,0.0001962685,0.002005404,0.004219218,0.0002164427,0.000006081706,0.001617708,9.799529e-7,0.8785685,0.02782326,0.007243364,0.07807498],"study_design_scores_gemma":[0.0003028164,0.00003868884,0.0007448971,0.0002074773,0.00006050844,0.000006545928,0.0001625965,0.00001143676,0.8537787,0.001738973,0.1427766,0.0001707357],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4515024,0.4154496,0.0002079293,0.0003829676,0.0002340965,0.0007322773,0.000007143346,0.00009624082,0.1313873],"genre_scores_gemma":[0.9631698,0.02093288,0.001344169,0.00006919183,0.0001352666,0.00009446767,0.00001252731,0.00002159472,0.01422017],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5116673,"threshold_uncertainty_score":0.9997221,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.10174946004771,"score_gpt":0.306055961473155,"score_spread":0.204306501425445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}