{"id":"W1970808007","doi":"10.1021/ol500902p","title":"Kinetic Diastereomer Differentiation in Au(III)- and Bi(III)-Catalyzed Benzylic Arylation: Concise and Stereocontrolled Synthesis of 2-Amino-1,1-diarylalkanes","year":2014,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Diastereomer; Stereoselectivity; Catalysis; Trifluoromethanesulfonate; Nitro; Reactivity (psychology); Stereochemistry; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001561167,0.0004184513,0.0001993418,0.0001067595,0.0001090967,0.0002292637,0.0002305729,0.0002397559,0.000716029],"category_scores_gemma":[0.0001161653,0.0001557422,0.0001216366,0.0001541038,0.000167674,0.0002452806,0.000262984,0.0003773774,0.0006858792],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00020697,"about_ca_system_score_gemma":0.0001966145,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005367315,"about_ca_topic_score_gemma":0.001743506,"domain_scores_codex":[0.9998875,0.00001727495,0.00001148645,0.00002026329,0.0000267775,0.00003666461],"domain_scores_gemma":[0.9999439,0.000008789829,0.00001641821,0.000008786627,0.00001101245,0.00001119094],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007633263,0.00001445583,0.00006092754,0.00006093428,0.000004477004,0.00005216515,0.00004264394,0.0001613598,0.9957866,0.0003239476,0.00007179566,0.003344344],"study_design_scores_gemma":[0.000006822467,0.00006035504,0.0001944587,0.000002103291,0.000004879984,0.00006417088,0.000007220518,0.0002868037,0.9976521,0.0000326008,0.001684845,0.000003639642],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.959633,0.003475954,0.01867052,0.000157531,0.00006962096,0.0000717012,0.0004953085,0.0002853278,0.01714095],"genre_scores_gemma":[0.9881173,0.001793483,0.006087348,0.00003707949,0.000008298665,0.00002655897,0.0002007136,0.00005076359,0.003678585],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000716029,"threshold_uncertainty_score":0.002395332,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006019386688376889,"score_gpt":0.1933074180532107,"score_spread":0.1872880313648338,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}