{"id":"W1970829419","doi":"10.1039/b705212j","title":"Metallotectons: using enantiopure tris(dipyrrinato)cobalt(iii) complexes to build chiral molecular materials","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Enantiopure drug; Tris; Cobalt; Tricarboxylic acid; Chemistry; Chiral resolution; Combinatorial chemistry; Stereochemistry; Organic chemistry; Enantiomer; Catalysis; Biochemistry; Enantioselective synthesis; Citric acid cycle; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001049809,0.000349006,0.00018767,0.0002210072,0.0001418288,0.0004675867,0.0004352354,0.0002420184,0.001085853],"category_scores_gemma":[0.0001980376,0.0001676016,0.0001126148,0.0001743899,0.0003052503,0.0003174958,0.0003131053,0.0004028257,0.000423891],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000349536,"about_ca_system_score_gemma":0.0001363595,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003830899,"about_ca_topic_score_gemma":0.0007010672,"domain_scores_codex":[0.9998868,0.00001187605,0.000007811398,0.00002670786,0.00003846647,0.00002830692],"domain_scores_gemma":[0.9999175,0.00001149677,0.00002317204,0.00001314451,0.00000935035,0.00002538711],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008768721,0.00003166487,0.0001649983,0.00007022935,0.000009042226,0.0001341363,0.0000313868,0.0002639534,0.9925705,0.001274084,0.0003336354,0.00502883],"study_design_scores_gemma":[0.00001360173,0.00008430854,0.0003311836,0.000001985379,0.000005023049,0.0001930215,0.000009116538,0.000495402,0.9959863,0.00007520141,0.002799533,0.000005341508],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9780124,0.001187269,0.009957052,0.0001739546,0.00008726805,0.00005575458,0.000319031,0.0005035079,0.00970374],"genre_scores_gemma":[0.9882108,0.0006204968,0.006944395,0.00005471279,0.00001489413,0.00002500731,0.0003125641,0.00006873708,0.003748529],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001085853,"threshold_uncertainty_score":0.003632545,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02325736325322875,"score_gpt":0.2835671272778217,"score_spread":0.260309764024593,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}