{"id":"W1970833088","doi":"10.1007/s00723-011-0262-0","title":"Spin-Selective Electron Transfer and Charge Recombination in Self-Assembled Porphyrin Naphthalenediimide Dyads","year":2011,"lang":"en","type":"article","venue":"Applied Magnetic Resonance","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Brock University","funders":"","keywords":"Intersystem crossing; Chemistry; Electron paramagnetic resonance; Porphyrin; Photochemistry; Singlet state; Electron transfer; Triplet state; Spin polarization; Electron; Spectroscopy; Nuclear magnetic resonance; Atomic physics; Excited state; Molecule; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001318484,0.0001938635,0.0001683218,0.0001062205,0.000155137,0.000259825,0.0002992235,0.0001420094,0.001004983],"category_scores_gemma":[0.0001219299,0.0001299171,0.00006661925,0.00009352999,0.0001772155,0.0002631937,0.0001643048,0.0003533793,0.0001992849],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003544136,"about_ca_system_score_gemma":0.0001055523,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003741484,"about_ca_topic_score_gemma":0.000625969,"domain_scores_codex":[0.9999436,0.000008982359,0.000002512163,0.00001256132,0.00001183834,0.00002049503],"domain_scores_gemma":[0.9999553,0.00001450229,0.000006603941,0.000005749632,0.000007085427,0.00001081073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008876613,0.00003063644,0.000103396,0.00004823876,0.000003382164,0.00005486918,0.0000655758,0.0001239854,0.9968651,0.000576519,0.0001199353,0.001919625],"study_design_scores_gemma":[0.00001342603,0.00006807682,0.0006092351,0.000001859294,0.000005374896,0.0000457024,0.00001678862,0.00151823,0.996792,0.00004613954,0.0008798193,0.000003284656],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995815,0.0003446451,0.001700206,0.00004844917,0.00001229998,0.000009003435,0.00002946757,0.00005039493,0.001990371],"genre_scores_gemma":[0.9962878,0.0001729646,0.0007574013,0.00001861254,0.000003731202,0.000007109497,0.0000447803,0.00001726138,0.002690366],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001004983,"threshold_uncertainty_score":0.00336206,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01065177502904696,"score_gpt":0.2150617565230223,"score_spread":0.2044099814939754,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}