{"id":"W1971067200","doi":"10.1021/ol8013182","title":"Aminoferrocene Lithiation by Boron Trifluoride Activation","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Chemistry; Electrophile; Boron trifluoride; Cyclopentadienyl complex; Yield (engineering); Boron; Ring (chemistry); Combinatorial chemistry; Sulfur; Medicinal chemistry; Group (periodic table); Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005510313,0.000159049,0.000133219,0.00003020317,0.0001724444,0.00002302876,0.000166403,0.0001153266,0.003386444],"category_scores_gemma":[0.0001148033,0.0001749955,0.00005423804,0.0002168985,0.00004271573,0.0002403289,0.00002837038,0.0001860101,0.00009673989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002368905,"about_ca_system_score_gemma":0.00004321948,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001347059,"about_ca_topic_score_gemma":6.934865e-7,"domain_scores_codex":[0.999038,0.000009272472,0.0002243812,0.0002729128,0.0002473877,0.0002080441],"domain_scores_gemma":[0.9994522,0.00005332363,0.0001258689,0.0002512415,0.00004263752,0.00007466745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001206154,0.00004934101,0.001197564,0.00002828634,0.00001974999,0.00000361641,0.000193038,0.000002303626,0.9735308,0.000008985246,0.02433038,0.0006239284],"study_design_scores_gemma":[0.0005234188,0.000004439204,0.0008746031,0.000009349311,0.00001321691,0.00001955917,0.0000392764,0.00003210191,0.9813056,0.000009359876,0.016971,0.0001980629],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919505,0.00003821011,0.001550972,0.00469815,0.00006779109,0.00003398247,0.00001141492,0.0001645447,0.00148444],"genre_scores_gemma":[0.9958338,0.00004110237,0.0001096888,0.001213036,0.0002871144,0.00000758067,0.0002659301,0.00003237581,0.002209382],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007774862,"threshold_uncertainty_score":0.9975246,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009773640936215364,"score_gpt":0.1987334848800176,"score_spread":0.1889598439438022,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}