{"id":"W1971217328","doi":"10.1021/ja053302f","title":"Extraordinary Cluster Formation and Intramolecular Ligand−Ligand Interactions in Cyanoactylene Mediated by Mg<sup>+</sup><sup>•</sup>:  Implications for the Atmospheric Chemistry of Titan and for Circumstellar Chemistry","year":2005,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Cyanoacetylene; Dissociation (chemistry); Ligand (biochemistry); Atmosphere of Titan; Propyne; Ion; Astrochemistry; Intramolecular force; Acetylene; Isotopologue; Computational chemistry; Physical chemistry; Photochemistry; Molecule; Stereochemistry; Interstellar medium; Methane; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001289421,0.0001598269,0.0001273178,0.00009562806,0.0003003794,0.000202051,0.0003360983,0.0001496241,0.0006649852],"category_scores_gemma":[0.0002155115,0.00007601914,0.00005915916,0.0001435706,0.0004255328,0.0001729534,0.0001964286,0.0001401136,0.0000798191],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004755435,"about_ca_system_score_gemma":0.0001556077,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002266635,"about_ca_topic_score_gemma":0.003049344,"domain_scores_codex":[0.9999048,0.00001184522,0.000002976678,0.00002473668,0.00003596064,0.00001970061],"domain_scores_gemma":[0.9999101,0.00002749577,0.00003053842,0.000008406601,0.00001191517,0.00001157926],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001778708,0.00001417752,0.002667121,0.00004100192,0.000008543093,0.0001124692,0.0001013903,0.0009440744,0.9940553,0.0002442405,0.0000514659,0.001582397],"study_design_scores_gemma":[0.00001643695,0.0001546202,0.008902296,0.000001931182,0.000006526224,0.0001264996,0.00005086467,0.005748539,0.9841802,0.00008303615,0.0007227593,0.000006224903],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9991028,0.0000684863,0.0003616738,0.00001454944,9.361162e-7,0.000002906616,0.00002864443,0.00001924632,0.0004007541],"genre_scores_gemma":[0.9993594,0.00002755849,0.0003353353,0.000004535849,7.32273e-7,0.000002771464,0.00005675506,0.000004497637,0.0002085372],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002266635,"threshold_uncertainty_score":0.004506886,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00669430146210332,"score_gpt":0.2548331281633432,"score_spread":0.2481388267012399,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}