{"id":"W1971355937","doi":"10.1021/ja001223s","title":"Reaction of the Cyclic Thionylphosphazene NSOCl[NPCl<sub>2</sub>]<sub>2</sub> with Halide Abstraction Agents:  An Ambient Temperature Ring-Opening Polymerization (ROP) Route to Poly(thionylphosphazenes)","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Polymerization; Polymer chemistry; Ring-opening polymerization; Reactivity (psychology); Phosphazene; Medicinal chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000539431,0.0003800606,0.0005929911,0.00003078771,0.0004051079,0.0001368734,0.0008320846,0.0001906477,0.00004677179],"category_scores_gemma":[0.0001057681,0.0002419589,0.0005241072,0.0008582597,0.0004048714,0.0005499249,0.0001312153,0.0007695668,0.00001250721],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000447365,"about_ca_system_score_gemma":0.0002265855,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002015351,"about_ca_topic_score_gemma":0.000009109469,"domain_scores_codex":[0.9969606,0.0001188242,0.0008892607,0.0004648566,0.00107158,0.0004948308],"domain_scores_gemma":[0.9971901,0.00008404726,0.001493514,0.0006670059,0.0002717057,0.0002936932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003876998,0.0002110059,0.001446781,0.00002558591,0.00007657406,0.00000357592,0.0007812158,0.0005271109,0.9917109,0.000002599249,0.000661844,0.004165104],"study_design_scores_gemma":[0.0006001654,0.0001519477,0.0202539,0.0002198249,0.000148881,0.0001879722,0.0008785685,0.00004060972,0.9770386,0.00001712011,0.0001626774,0.0002997665],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977334,0.0001132998,0.00003019406,0.001417508,0.0003430904,0.0002409304,0.00002274194,0.00004582141,0.00005306705],"genre_scores_gemma":[0.9970093,0.0002321042,0.0003675879,0.001823172,0.000454593,0.0000123592,0.000009457796,0.00005530872,0.00003608216],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01880712,"threshold_uncertainty_score":0.9866797,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006836488096592966,"score_gpt":0.226843392929258,"score_spread":0.2200069048326651,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}