{"id":"W1971355937","doi":"10.1021/ja001223s","title":"Reaction of the Cyclic Thionylphosphazene NSOCl[NPCl<sub>2</sub>]<sub>2</sub> with Halide Abstraction Agents:  An Ambient Temperature Ring-Opening Polymerization (ROP) Route to Poly(thionylphosphazenes)","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Polymerization; Polymer chemistry; Ring-opening polymerization; Reactivity (psychology); Phosphazene; Medicinal chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009935821,0.0003508222,0.000141126,0.00009063604,0.00009022264,0.0001887755,0.000174031,0.0002783723,0.0008916122],"category_scores_gemma":[0.0001295512,0.0001509705,0.0001809322,0.00009634373,0.000200139,0.000237269,0.0002073737,0.0003231979,0.0002306056],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001957995,"about_ca_system_score_gemma":0.0002057748,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000401247,"about_ca_topic_score_gemma":0.001011707,"domain_scores_codex":[0.9999245,0.00000950309,0.000005474451,0.00001702729,0.00002427639,0.00001915577],"domain_scores_gemma":[0.9999307,0.000009705732,0.00003000467,0.000006461824,0.000008741104,0.00001433405],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002607861,0.000004951925,0.00004360952,0.00003939311,0.000003832391,0.00004239953,0.000015758,0.0001354468,0.9986491,0.00008600898,0.0000166809,0.0009367505],"study_design_scores_gemma":[0.000002768976,0.00009764263,0.0003615211,0.000001878686,0.000004915845,0.00006845767,0.000006548065,0.0003763629,0.9980929,0.00001640641,0.0009673944,0.000003232732],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893727,0.0006512612,0.007462722,0.00004956749,0.00002631049,0.00005467477,0.000103976,0.00007690169,0.002201925],"genre_scores_gemma":[0.9926985,0.0005194863,0.004588302,0.00002067563,0.000004969819,0.00002984717,0.00007203654,0.00001553933,0.002050739],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008916122,"threshold_uncertainty_score":0.002982795,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006836488096592966,"score_gpt":0.226843392929258,"score_spread":0.2200069048326651,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}