{"id":"W1971360527","doi":"10.1021/ma010293w","title":"A Novel and Versatile Methodology for Functionalization of Conjugated Polymers. Transformation of Poly(3-bromo-4-hexylthiophene) via Palladium-Catalyzed Coupling Chemistry","year":2001,"lang":"en","type":"article","venue":"Macromolecules","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":73,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Palladium; Conjugated system; Surface modification; Polymer; Catalysis; Polymer chemistry; Coupling (piping); Chemistry; Coupling reaction; Combinatorial chemistry; Materials science; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002384762,0.0002022288,0.0003681486,0.000075526,0.0001105145,0.00001627408,0.0001252163,0.0002168702,0.0003814682],"category_scores_gemma":[0.0001911309,0.0002296144,0.000130905,0.0002064796,0.0002289971,0.0001095957,0.00003023001,0.0001076391,0.000001418723],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006594152,"about_ca_system_score_gemma":0.00008709668,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004480161,"about_ca_topic_score_gemma":0.00002361721,"domain_scores_codex":[0.9986876,0.000001846465,0.0005762409,0.0003000369,0.0001978077,0.0002364457],"domain_scores_gemma":[0.9987366,0.000341285,0.0003560511,0.0002635055,0.0002276724,0.00007483636],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003591747,0.0001201495,0.0002801363,0.0005339761,0.0001358535,0.000001047315,0.0005121892,0.0002491976,0.9960167,0.0002189256,0.000004960292,0.001567652],"study_design_scores_gemma":[0.002023666,0.00002005352,0.0002536806,0.00007082584,0.0001691078,0.0001111057,0.0004497837,0.01469964,0.9815339,0.0002868819,0.0001868687,0.0001944169],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8686398,0.0004147582,0.1300101,0.00009486632,0.00006564959,0.0001526873,0.0002810876,0.00005917068,0.0002818254],"genre_scores_gemma":[0.9969375,0.00005221791,0.001768504,0.00001505737,0.00005131549,0.00003869001,0.0009764996,0.00003640642,0.0001238393],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1282976,"threshold_uncertainty_score":0.9363405,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03064551342855317,"score_gpt":0.2800054302585775,"score_spread":0.2493599168300243,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}