{"id":"W1971362914","doi":"10.1021/jp020710m","title":"Hyperfine Interactions in HSiCl","year":2002,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Isotopomers; Quadrupole; Hyperfine structure; Coupling constant; Hyperfine coupling; Spectral line; Atomic physics; Microwave; Ab initio; Ab initio quantum chemistry methods; Chemistry; Rotation (mathematics); Nuclear magnetic resonance; Physics; Molecule; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005538593,0.00009833511,0.0001632558,0.000009956879,0.00003921184,0.00001300076,0.0002717568,0.00002810481,0.002169635],"category_scores_gemma":[0.00006175414,0.00006398611,0.0001182987,0.00009802984,0.00005174566,0.00005977307,0.00002756897,0.0006610375,0.00001131436],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004708295,"about_ca_system_score_gemma":0.000009568862,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003055196,"about_ca_topic_score_gemma":0.000001047077,"domain_scores_codex":[0.9994146,0.00001341857,0.0001978473,0.00006263907,0.0001760483,0.0001354303],"domain_scores_gemma":[0.9994932,0.00008398855,0.0001445509,0.0001842278,0.00003680079,0.00005724834],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003586953,0.0001296735,0.00002721887,0.00002588377,0.0000231829,0.00002943385,0.0003689138,0.000441783,0.997977,0.00003320256,0.0004693626,0.0004385188],"study_design_scores_gemma":[0.0003861903,0.00001419331,0.00004620594,0.00005566372,0.00003593796,0.0003095276,0.0001287704,0.004233605,0.9904732,0.0008282099,0.003404479,0.00008408709],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9639954,0.0001723006,0.00005562906,0.0005467974,0.00001573292,0.000009145811,0.000002601434,0.000006543629,0.03519584],"genre_scores_gemma":[0.9980971,0.00001911563,0.00002349261,0.00004687277,0.0006128926,6.509995e-7,5.968431e-7,0.000008692018,0.001190536],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03410174,"threshold_uncertainty_score":0.9987425,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0101464025473742,"score_gpt":0.2536482971410392,"score_spread":0.243501894593665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}