{"id":"W1971362914","doi":"10.1021/jp020710m","title":"Hyperfine Interactions in HSiCl","year":2002,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Isotopomers; Quadrupole; Hyperfine structure; Coupling constant; Hyperfine coupling; Spectral line; Atomic physics; Microwave; Ab initio; Ab initio quantum chemistry methods; Chemistry; Rotation (mathematics); Nuclear magnetic resonance; Physics; Molecule; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001195599,0.0001374829,0.0001107899,0.0006752695,0.0005213482,0.0003072974,0.0002352536,0.0002423899,0.005184192],"category_scores_gemma":[0.0002073852,0.0001665225,0.00007516968,0.000344931,0.0004025669,0.0002271978,0.000381251,0.0002540699,0.0003621014],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006600306,"about_ca_system_score_gemma":0.0002262529,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00504613,"about_ca_topic_score_gemma":0.01025594,"domain_scores_codex":[0.9999095,0.000006520041,0.000001518705,0.00002378529,0.00002698518,0.00003167867],"domain_scores_gemma":[0.9998963,0.00003072461,0.00001845928,0.00001000287,0.0000289389,0.00001550758],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003628036,0.00008029736,0.01181282,0.000168053,0.00002449863,0.0005921746,0.0009806894,0.005204312,0.9513785,0.009317255,0.001702916,0.01837564],"study_design_scores_gemma":[0.0003516264,0.0008868035,0.1274466,0.0001261665,0.00006954154,0.001084166,0.002565047,0.07157619,0.7562398,0.01553304,0.02394642,0.000174615],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895083,0.0002579963,0.001193678,0.0001491095,0.00000631189,0.000008641065,0.00007691685,0.0001039308,0.008694979],"genre_scores_gemma":[0.9983901,0.00003853459,0.0001786966,0.00004988511,0.000001751846,0.000004148274,0.00007995417,0.000006951533,0.001250047],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005184192,"threshold_uncertainty_score":0.01734287,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0101464025473742,"score_gpt":0.2536482971410392,"score_spread":0.243501894593665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}