{"id":"W1971984421","doi":"10.1002/chin.200929054","title":"ChemInform Abstract: Oxidative Friedel—Crafts Reaction and Its Application to the Total Syntheses of Amaryllidaceae Alkaloids.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Chemistry; Friedel–Crafts reaction; Amaryllidaceae Alkaloids; Service (business); Amaryllidaceae; Combinatorial chemistry; Organic chemistry; Business; Alkaloid; Catalysis; Botany; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003719057,0.0008377231,0.0003821139,0.0007097597,0.0004536806,0.0004122765,0.0007101643,0.0004954528,0.007896664],"category_scores_gemma":[0.0002826524,0.0002953184,0.0004669754,0.0007658668,0.0003062486,0.000677662,0.0007375891,0.001098564,0.004007847],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003748382,"about_ca_system_score_gemma":0.0006371217,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006875831,"about_ca_topic_score_gemma":0.001234148,"domain_scores_codex":[0.9998274,0.00002214834,0.00001103788,0.00003190837,0.00007078041,0.00003664497],"domain_scores_gemma":[0.9999402,0.00001196876,0.00001084653,0.00001149042,0.000009860717,0.00001558096],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0008839676,0.0003598593,0.0003324705,0.002374725,0.0002651508,0.001290463,0.0005095128,0.003036803,0.7141681,0.01638447,0.01920789,0.2411866],"study_design_scores_gemma":[0.0002829767,0.00228526,0.001732549,0.0001880867,0.0001863644,0.001668551,0.00007052164,0.00425323,0.8526482,0.004277751,0.1323002,0.0001062485],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.4767094,0.05334584,0.2376288,0.002622315,0.003255753,0.001124074,0.006316942,0.003851512,0.2151454],"genre_scores_gemma":[0.8516881,0.03464768,0.04521476,0.0007104016,0.0004475217,0.0002850406,0.003162985,0.0003213982,0.06352205],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.007896664,"threshold_uncertainty_score":0.02641696,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01134736208115998,"score_gpt":0.233450942195471,"score_spread":0.222103580114311,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}