{"id":"W1972313514","doi":"10.1080/03601230801941667","title":"Trace level determination of selected organophosphorus pesticides and their degradation products in environmental air samples by liquid chromatography-positive ion electrospray tandem mass spectrometry","year":2008,"lang":"en","type":"article","venue":"Journal of Environmental Science and Health Part B","topic":"Pesticide Residue Analysis and Safety","field":"Agricultural and Biological Sciences","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"","keywords":"Chemistry; Chromatography; Detection limit; Formic acid; Tandem mass spectrometry; Oxon; Electrospray; Mass spectrometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008293667,0.0001293893,0.0002847092,0.00007140704,0.0003406356,0.00001397188,0.0001200643,0.00004643308,0.00002669662],"category_scores_gemma":[0.00003828756,0.00006156558,0.00003392923,0.0005746409,0.0004130722,0.0003535879,0.00002789866,0.0001305316,3.809344e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000181737,"about_ca_system_score_gemma":0.00005690779,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008981147,"about_ca_topic_score_gemma":0.00007037231,"domain_scores_codex":[0.9985488,0.00007631537,0.0004475125,0.0002400367,0.0004063408,0.0002810061],"domain_scores_gemma":[0.9992792,0.00008796373,0.0004287819,0.00003459414,0.00002125819,0.0001482065],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00003227037,0.0001382312,0.09689638,0.000003902468,0.000004721133,0.000002559308,0.0001528351,0.000001360953,0.8944975,0.000002251293,0.00002312898,0.008244871],"study_design_scores_gemma":[0.0001341253,0.001171115,0.7549939,0.00002451739,0.000006598775,0.00008433477,0.000306676,0.00002793877,0.2430598,0.00002261529,0.00009126441,0.00007710555],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964706,0.00230165,0.00008066459,0.0009369656,0.00001762855,0.0001358502,0.00004701311,0.000002609039,0.000007028116],"genre_scores_gemma":[0.991701,0.007658522,0.0004858598,0.00009113848,0.00003829577,0.000001519079,0.00001618097,0.000001192823,0.000006268257],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6580976,"threshold_uncertainty_score":0.2619928,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02104645228716409,"score_gpt":0.2300446663496487,"score_spread":0.2089982140624846,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}