{"id":"W1972346271","doi":"10.1139/v10-154","title":"The use of a silica-based heat sink to “uncouple” the matrix-assisted laser desorption/ionization (MALDI) mechanism","year":2011,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Desorption; Yield (engineering); Ion; Ionization; Heat sink; Thermal ionization; Analytical Chemistry (journal); Laser; Matrix-assisted laser desorption/ionization; Chromatography; Adsorption; Electron ionization; Thermodynamics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003971877,0.0005715283,0.0002748784,0.0002867439,0.0001857321,0.0004270404,0.0003225413,0.0003257385,0.0008096038],"category_scores_gemma":[0.0007430646,0.0002993953,0.0002188593,0.000168399,0.0005911604,0.0007562065,0.0003993694,0.0004537364,0.0003273336],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000271768,"about_ca_system_score_gemma":0.0004201977,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003450061,"about_ca_topic_score_gemma":0.0006245738,"domain_scores_codex":[0.9998206,0.00002485097,0.00001059827,0.0000528054,0.00005940163,0.00003178191],"domain_scores_gemma":[0.9993839,0.0003186094,0.0001068871,0.00006393774,0.00009147669,0.00003510369],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004309586,0.000006249913,0.00009622268,0.00003025988,0.00000227134,0.00001036643,0.000008314099,0.00005303335,0.9988569,0.00005390113,0.00001006391,0.0008293609],"study_design_scores_gemma":[0.000003535928,0.0000497508,0.0003587795,0.000001077665,0.000003139801,0.00002868942,0.000004421007,0.0006774968,0.9985025,0.00002078613,0.0003466351,0.000003261842],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9496499,0.0008174333,0.04747693,0.0001284117,0.0000758769,0.0001318742,0.0001759746,0.0003510072,0.001192606],"genre_scores_gemma":[0.9227844,0.0009022151,0.0730728,0.0001718184,0.00003520477,0.0001230491,0.0003511406,0.0001377425,0.002421633],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008096038,"threshold_uncertainty_score":0.002708435,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03176029450880963,"score_gpt":0.2306784736698547,"score_spread":0.1989181791610451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}