{"id":"W1972349468","doi":"10.1016/j.jpcs.2007.07.057","title":"Volatile hafnium(IV) compounds with beta-diketonate and cyclopentadienyl derivatives","year":2007,"lang":"en","type":"article","venue":"Journal of Physics and Chemistry of Solids","topic":"Semiconductor materials and devices","field":"Engineering","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"Petroleum Technology Alliance Canada","keywords":"Cyclopentadienyl complex; Hafnium; Chemistry; Mass spectrometry; Vaporization; Analytical Chemistry (journal); Thermogravimetric analysis; Monoclinic crystal system; Tetrahydrofuran; Inorganic chemistry; Organic chemistry; Crystal structure; Zirconium","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001010415,0.0001059604,0.0002415246,0.00001231698,0.00002622794,0.00003399893,0.000062599,0.00003533397,0.00001377868],"category_scores_gemma":[0.000001775478,0.00008245098,0.00002787186,0.00004372799,0.0000807528,0.0001498015,0.000017368,0.00009164619,1.086089e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009812395,"about_ca_system_score_gemma":0.00001037271,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003286762,"about_ca_topic_score_gemma":5.566826e-7,"domain_scores_codex":[0.9994863,0.0000024134,0.0002339009,0.00005817056,0.000109709,0.0001095412],"domain_scores_gemma":[0.9996361,0.00002826877,0.0001405537,0.00005704719,0.00006585675,0.00007220234],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003203492,0.00001957914,0.003279506,0.0002292763,0.00008942263,0.000005622996,0.0003153873,0.00007363724,0.9950603,0.00004611032,0.00008444798,0.0007646295],"study_design_scores_gemma":[0.0004776887,0.00005844272,0.004696139,0.0001229107,0.00003752891,0.00006766167,0.0003126989,0.0001793337,0.9926814,0.0004376681,0.000804729,0.0001237672],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968844,0.0006666406,0.0002345038,0.00001123736,0.00005097617,0.00001717762,0.000006095415,0.000007134779,0.002121802],"genre_scores_gemma":[0.9990808,0.0001182922,0.0005631075,0.00000909238,0.000198575,2.131208e-7,0.000001626721,0.0000124374,0.00001582562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002378915,"threshold_uncertainty_score":0.3362253,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008006526471288014,"score_gpt":0.2102676888098586,"score_spread":0.2022611623385706,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}