{"id":"W1972514222","doi":"10.1016/s0022-328x(00)00735-x","title":"Early transition metal and lanthanide bis(iminophosphorano)methandiide complexes; ‘pincer’ and bridging bis(phosphorus) metal carbenes","year":2001,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":155,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Carbene; Pincer movement; Medicinal chemistry; Deprotonation; Alkylation; Main group element; Alkyl; Transition metal; Polymer chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001385669,0.0002404463,0.0001809494,0.0002205601,0.0002703116,0.0007213421,0.000461336,0.0002592183,0.0031196],"category_scores_gemma":[0.000334961,0.0002245261,0.00006741394,0.0001546967,0.0003184483,0.0006629255,0.0004776872,0.0003170684,0.0004053386],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004595203,"about_ca_system_score_gemma":0.000110983,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004039216,"about_ca_topic_score_gemma":0.0005989324,"domain_scores_codex":[0.9999133,0.00001281765,0.000003877069,0.0000205186,0.00002112229,0.00002833406],"domain_scores_gemma":[0.9999459,0.00001630475,0.000009204637,0.000009719199,0.000006107531,0.00001277978],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002342042,0.00009652915,0.0006760988,0.0004557074,0.00002215139,0.0006253175,0.0004051596,0.0008604494,0.945784,0.02549179,0.001845293,0.02139557],"study_design_scores_gemma":[0.00003665646,0.0001491797,0.0005718175,0.000007450807,0.00001001656,0.0002885681,0.00006128613,0.0009322325,0.9845865,0.001068263,0.01227906,0.00000904116],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9532889,0.00415901,0.003909748,0.0002688676,0.00009414442,0.00003860574,0.0001743356,0.0002510446,0.03781527],"genre_scores_gemma":[0.9897553,0.0006140814,0.0008831313,0.00004359371,0.00001348919,0.00001151478,0.0001188357,0.00003826976,0.008521854],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0031196,"threshold_uncertainty_score":0.01043606,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01229279521464864,"score_gpt":0.2159750797751495,"score_spread":0.2036822845605009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}