{"id":"W1972519703","doi":"10.1039/c2ob07176b","title":"SBA-15-functionalized palladium complex partially confined with ionic liquid: an efficient and reusable catalyst system for aqueous-phase Suzuki reaction","year":2012,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute for Advanced Studies in Basic Sciences; Iran National Science Foundation; McGill University","keywords":"Chemistry; Catalysis; Hexafluorophosphate; Ionic liquid; Aryl; Palladium; Halide; Aqueous solution; Sorption; Heterogeneous catalysis; Homogeneous catalysis; Aqueous two-phase system; Suzuki reaction; Aryl halide; Organic chemistry; Inorganic chemistry; Alkyl; Adsorption","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003282747,0.0004595059,0.0004540153,0.00004752479,0.0004318258,0.0001743257,0.0002530966,0.0003304689,0.0007731392],"category_scores_gemma":[0.0001287222,0.0004590909,0.000140508,0.0002729986,0.0002360437,0.0001355861,0.0000916119,0.0002517073,0.00003829696],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005658864,"about_ca_system_score_gemma":0.0003201235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001036995,"about_ca_topic_score_gemma":0.00001359965,"domain_scores_codex":[0.9975762,0.000003199934,0.0005270081,0.0007539712,0.0004204597,0.000719116],"domain_scores_gemma":[0.9977721,0.00008651896,0.0003415371,0.00102263,0.0002787924,0.000498409],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008652204,0.0006483863,0.0000881539,0.0007874373,0.0002138759,0.00002160818,0.0001032499,0.000009699387,0.997016,0.00004450748,0.0001163145,0.00008561039],"study_design_scores_gemma":[0.004115224,0.0001109816,0.00003276589,0.0001317244,0.0004299617,0.001065001,0.0005169424,0.001825966,0.9857963,0.000002703184,0.005420185,0.0005522574],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9890048,0.0004862193,0.008740137,0.0001292174,0.0001346464,0.0003318116,0.0002220663,0.000412895,0.0005382051],"genre_scores_gemma":[0.9959055,0.000007981874,0.0001257318,0.0000338065,0.0004284332,0.0001341435,0.002603622,0.000130915,0.0006298946],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01121965,"threshold_uncertainty_score":0.9997861,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01444485168360187,"score_gpt":0.2638125246770504,"score_spread":0.2493676729934485,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}