{"id":"W1972532356","doi":"10.1021/ol0621710","title":"Total Synthesis and Stereochemical Confirmation of Manassantin A, B, and B<sub>1</sub>","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Total synthesis; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002728129,0.0008923715,0.0004226003,0.0005558059,0.0005588843,0.000324378,0.0005154845,0.0003184416,0.004091498],"category_scores_gemma":[0.0002225042,0.0001779795,0.0003393104,0.0005734551,0.0004016219,0.0004542969,0.0004614559,0.000907897,0.001592133],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003764073,"about_ca_system_score_gemma":0.0008959263,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001400071,"about_ca_topic_score_gemma":0.001526664,"domain_scores_codex":[0.999851,0.00002889473,0.00001332955,0.00003547618,0.00002863208,0.00004263451],"domain_scores_gemma":[0.9998079,0.00001986089,0.00003341222,0.00003876414,0.00004950714,0.00005064726],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004510384,0.0001806826,0.0001968919,0.0002864574,0.00003957123,0.0003874706,0.0001197356,0.0004965469,0.9497293,0.002946133,0.0008633168,0.0443028],"study_design_scores_gemma":[0.0000651798,0.00113588,0.0009552828,0.00002306878,0.00004160022,0.0005406237,0.00007065929,0.0002830534,0.9717546,0.001035821,0.02405922,0.00003502725],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7864052,0.01530574,0.1260061,0.0005788347,0.0007327679,0.001069144,0.005451332,0.0009076435,0.0635433],"genre_scores_gemma":[0.9338595,0.008678843,0.03832101,0.0002078622,0.0001002709,0.0002420875,0.003054902,0.0001586261,0.01537689],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004091498,"threshold_uncertainty_score":0.01368743,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003545581115339423,"score_gpt":0.173684220948529,"score_spread":0.1701386398331896,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}