{"id":"W1972665175","doi":"10.1002/mats.201200043","title":"Termination of Surface Radicals and Kinetic Analysis of Surface‐Initiated RAFT Polymerization on Flat Surfaces","year":2012,"lang":"en","type":"article","venue":"Macromolecular Theory and Simulations","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Raft; Radical; Reversible addition−fragmentation chain-transfer polymerization; Chain transfer; Surface (topology); Polymer; Polymerization; Radical polymerization; Chemistry; Polymer chemistry; Surface modification; Chemical physics; Photochemistry; Materials science; Physical chemistry; Organic chemistry; Geometry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001341367,0.0002971111,0.0002601053,0.0004072438,0.0002383882,0.0002609083,0.0004719657,0.0003448049,0.001874095],"category_scores_gemma":[0.0003543184,0.0002053957,0.0002679798,0.000195755,0.0002687487,0.0004477719,0.0001424687,0.0004691495,0.0003555271],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005392815,"about_ca_system_score_gemma":0.0001900498,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001987063,"about_ca_topic_score_gemma":0.0009009585,"domain_scores_codex":[0.9999088,0.000007507701,0.00000264675,0.00001567478,0.0000371836,0.00002821136],"domain_scores_gemma":[0.999872,0.00006397128,0.00001904776,0.00001090746,0.00002137215,0.00001268476],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000298051,0.0001925452,0.00141637,0.0002125738,0.00004086121,0.0005346423,0.0001965362,0.1801513,0.7991933,0.008457512,0.0005097469,0.00879656],"study_design_scores_gemma":[0.00002539465,0.0001335996,0.001740078,0.000007427975,0.000006714592,0.00004266893,0.00003441137,0.7898957,0.2064575,0.00101359,0.0006160599,0.00002680588],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9838653,0.0003592862,0.01185023,0.00007344331,0.00001981851,0.00003503806,0.0001566265,0.0001520318,0.003488138],"genre_scores_gemma":[0.9962287,0.0001938778,0.002166006,0.00001212236,0.000003693873,0.00002691319,0.0001089226,0.00001649431,0.001243352],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001987063,"threshold_uncertainty_score":0.006269455,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01810044134765967,"score_gpt":0.2998796447104882,"score_spread":0.2817792033628286,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}