{"id":"W1972845883","doi":"10.1016/j.jms.2009.07.003","title":"Infrared spectra of two isomers of OCS–C2H2 and OCS–C2D2 in the region of OCS ν1 fundamental","year":2009,"lang":"en","type":"article","venue":"Journal of Molecular Spectroscopy","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"Steacie Institute for Molecular Sciences; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Infrared; Spectral line; Excited state; Materials science; Infrared spectroscopy; Microwave; Ground state; Argon; Rotational spectroscopy; Atomic physics; Jet (fluid); Cis–trans isomerism; Molecular physics; Analytical Chemistry (journal); Physics; Optics; Chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001568199,0.0003057833,0.0001352981,0.0005084077,0.0004422541,0.0001430076,0.0005610259,0.0004615566,0.008438283],"category_scores_gemma":[0.0003204143,0.0000805093,0.0001048755,0.0005997379,0.0004841912,0.0002440934,0.0001855676,0.0004818054,0.0002566746],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003348333,"about_ca_system_score_gemma":0.0001417097,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002548551,"about_ca_topic_score_gemma":0.001516727,"domain_scores_codex":[0.9998422,0.00001179941,0.000003854137,0.00003144639,0.00004950096,0.00006125309],"domain_scores_gemma":[0.9997628,0.00007865591,0.0000367403,0.00001868261,0.00005085827,0.00005225685],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002372789,0.0001564078,0.002646926,0.0001232104,0.00002742324,0.0003127357,0.0001825926,0.0008039193,0.9811637,0.00189332,0.001770704,0.008546361],"study_design_scores_gemma":[0.0001713715,0.0009240662,0.05515139,0.00001900795,0.00004002767,0.00062401,0.0008182148,0.01110056,0.9217001,0.00101363,0.008354466,0.00008326984],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9872922,0.0003726587,0.001169513,0.0001795175,0.00004967476,0.000009134473,0.0005383712,0.00003812707,0.01035083],"genre_scores_gemma":[0.9974585,0.00006956564,0.0004390259,0.00007308085,0.0000116321,0.000005959894,0.0004073171,0.000009197324,0.001525677],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008438283,"threshold_uncertainty_score":0.02822888,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005929689427246148,"score_gpt":0.2615424978486132,"score_spread":0.2556128084213671,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}