{"id":"W1973017004","doi":"10.1021/jp0640878","title":"Diffusion Kinetics for Methanol in Polycrystalline Ice","year":2006,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Crystallite; Kinetics; Sublimation (psychology); Desorption; Methanol; Mole fraction; Isothermal process; Analytical Chemistry (journal); Thermal desorption; Annealing (glass); Ice crystals; Thermodynamics; Crystallography; Adsorption; Physical chemistry; Chromatography; Organic chemistry; Meteorology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001130011,0.0002404248,0.0002547505,0.0002182537,0.000165079,0.0003675873,0.0003653228,0.0002214928,0.002251991],"category_scores_gemma":[0.0004174761,0.0001801393,0.0001845177,0.0001968917,0.0002479503,0.0006402289,0.0001606895,0.0003905799,0.0003579782],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007156869,"about_ca_system_score_gemma":0.0001876081,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002509992,"about_ca_topic_score_gemma":0.002223773,"domain_scores_codex":[0.9998953,0.000004486594,0.000004843426,0.00004327558,0.00003038963,0.00002162613],"domain_scores_gemma":[0.9997811,0.0001134502,0.00004131095,0.00001380046,0.00003959347,0.0000107238],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001233255,0.00001803061,0.0008913928,0.0001160264,0.000007424717,0.00007392629,0.000101952,0.0007408022,0.9936438,0.0002901157,0.00007938095,0.003913809],"study_design_scores_gemma":[0.00002086177,0.00008395645,0.004035071,0.00001271575,0.000008638405,0.0001083526,0.00007498041,0.01219525,0.9817229,0.0001711642,0.001555323,0.00001080511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893612,0.001686465,0.005628483,0.0001101306,0.00002035429,0.00003510606,0.0006734896,0.00006263634,0.002421987],"genre_scores_gemma":[0.9924879,0.001448597,0.002794964,0.00002460443,0.00000769805,0.00004353658,0.0005507837,0.00003575734,0.00260606],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002509992,"threshold_uncertainty_score":0.00753361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00788654330424964,"score_gpt":0.2152763481122951,"score_spread":0.2073898048080454,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}