{"id":"W1973097029","doi":"10.1021/ja305491t","title":"A Tunable Route for the Synthesis of Azomethine Imines and β-Aminocarbonyl Compounds from Alkenes","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; University of Ottawa; AstraZeneca Canada","keywords":"Chemistry; Alkene; Reagent; Steric effects; Isocyanate; Hydrazone; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003476489,0.0001208901,0.0003550779,0.000006498679,0.00006670322,0.00001387333,0.000338519,0.00006080248,0.000005559564],"category_scores_gemma":[0.0004197129,0.00006204373,0.0006733393,0.0001211001,0.0004207563,0.000006076395,0.0001513923,0.0001084569,9.405862e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001918217,"about_ca_system_score_gemma":0.00002342727,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001194932,"about_ca_topic_score_gemma":0.000001287559,"domain_scores_codex":[0.9991912,0.00003472688,0.0003059839,0.0001096171,0.0001722356,0.0001862167],"domain_scores_gemma":[0.9985536,0.0005094944,0.0005384095,0.0002230469,0.00009650771,0.00007899245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006325881,0.00006623074,0.01199532,0.00001040606,0.0004870517,2.971933e-8,0.00005932343,0.00000305391,0.9809325,0.000002405122,0.003600181,0.002780263],"study_design_scores_gemma":[0.0001683059,0.0000302104,0.004798379,0.00001959238,0.0004063534,0.000007755089,0.0003425771,0.000122791,0.9867989,0.0000725619,0.007142356,0.00009019923],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995266,0.002666988,0.0003173286,0.00159193,0.00004697885,0.00004709325,0.00003384923,0.000001515235,0.00002833849],"genre_scores_gemma":[0.9949268,0.0006457574,0.003392872,0.0004099239,0.0005676142,0.000005776148,0.000002623569,0.00001262729,0.000035972],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007196945,"threshold_uncertainty_score":0.253007,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01027107779357416,"score_gpt":0.246465118024437,"score_spread":0.2361940402308629,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}