{"id":"W1973195044","doi":"10.1002/aoc.1265","title":"Synthesis and spectroscopic characterization of dimethyl/di(<i>n</i>‐butyl)tin(IV)bis(<i>O</i>,<i>O</i>′‐ditolyl dithiophosphate) complexes. Crystal structures of Me<sub>2</sub>Sn[S<sub>2</sub>P(OC<sub>6</sub>H<sub>4</sub>Me‐<i>o</i>)<sub>2</sub>]<sub>2</sub> and <i>n</i>‐Bu<sub>2</sub>Sn[S<sub>2</sub>P(OC<sub>6</sub>H<sub>4</sub>Me‐<i>o</i>)<sub>2</sub>]<sub>2</sub>","year":2007,"lang":"en","type":"article","venue":"Applied Organometallic Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Tin; Bipyramid; Crystal structure; Benzene; Molecule; Crystallography; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","open_science","research_integrity"],"category_scores_codex":[0.009250074,0.02034975,0.02097797,0.006307018,0.007382407,0.005512859,0.01186366,0.01307681,0.0005434048],"category_scores_gemma":[0.003934599,0.02362564,0.008516244,0.01582376,0.00941597,0.007579233,0.008903691,0.01437193,0.001674932],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.006987517,"about_ca_system_score_gemma":0.005864189,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001601203,"about_ca_topic_score_gemma":0.0008529362,"domain_scores_codex":[0.9226464,0.003019969,0.02176873,0.02058727,0.01430544,0.01767218],"domain_scores_gemma":[0.9421395,0.006945251,0.02004011,0.01535139,0.005401193,0.01012253],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.005793226,0.008110215,0.003026333,0.01174262,0.008202197,0.001279018,0.002501264,0.0003805496,0.9079867,0.0004330293,0.002326431,0.0482184],"study_design_scores_gemma":[0.0174858,0.001457587,0.009868222,0.004729614,0.009885599,0.002275941,0.002234222,0.0007564571,0.9270766,0.001765116,0.001694703,0.02077015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9542522,0.007003163,0.003007627,0.001087617,0.005429022,0.01143271,0.01104695,0.005409573,0.001331112],"genre_scores_gemma":[0.927278,0.03336236,0.0005697317,0.002222098,0.009298919,0.003952221,0.01651306,0.006732602,0.00007104274],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02744825,"threshold_uncertainty_score":0.9997717,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006050721839403975,"score_gpt":0.1936918839450854,"score_spread":0.1876411621056814,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}