{"id":"W1973274944","doi":"10.1021/ic020041r","title":"Synthesis, Characterization, and Solution Redox Properties of (trimpsi)M(CO)<sub>2</sub>(NO) Complexes [M = V, Nb, Ta; trimpsi = <sup>t</sup>BuSi(CH<sub>2</sub>PMe<sub>2</sub>)<sub>3</sub>]","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Phosphine; Bimetallic strip; Microcrystalline; Crystallography; Vanadium; Redox; Medicinal chemistry; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0008858112,0.00221755,0.002846021,0.0004269124,0.001099811,0.000566529,0.001805098,0.001540327,0.0022196],"category_scores_gemma":[0.001653428,0.002351681,0.001051981,0.001684504,0.001287364,0.001025483,0.0009762004,0.001405759,0.0006348188],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009330739,"about_ca_system_score_gemma":0.0005120254,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004160797,"about_ca_topic_score_gemma":0.00002433702,"domain_scores_codex":[0.9894226,0.0002657632,0.003261924,0.002901799,0.001934452,0.002213531],"domain_scores_gemma":[0.9924991,0.0005692103,0.001984687,0.002999296,0.0009645783,0.0009831825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002586235,0.001247157,0.0006410526,0.002613009,0.0009792033,0.00004708082,0.0008459289,0.00001505423,0.960188,0.0000105352,0.00174954,0.03140486],"study_design_scores_gemma":[0.001983274,0.00007585225,0.001059774,0.0009402547,0.001094475,0.0003533208,0.0005516742,0.001327353,0.9870983,0.00005331306,0.002995323,0.00246707],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924475,0.0029162,0.0001389655,0.0006380824,0.0002022725,0.0007190838,0.001009179,0.0007864017,0.001142348],"genre_scores_gemma":[0.9908968,0.004997398,0.00005493126,0.0001847035,0.001559608,0.0003155612,0.00110516,0.0005289539,0.0003568617],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02893779,"threshold_uncertainty_score":0.9997559,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01467193043407758,"score_gpt":0.189595869574181,"score_spread":0.1749239391401034,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}