{"id":"W1973274944","doi":"10.1021/ic020041r","title":"Synthesis, Characterization, and Solution Redox Properties of (trimpsi)M(CO)<sub>2</sub>(NO) Complexes [M = V, Nb, Ta; trimpsi = <sup>t</sup>BuSi(CH<sub>2</sub>PMe<sub>2</sub>)<sub>3</sub>]","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Phosphine; Bimetallic strip; Microcrystalline; Crystallography; Vanadium; Redox; Medicinal chemistry; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007531698,0.0001800948,0.0001637564,0.0001556905,0.0001373218,0.0003071363,0.0002421001,0.000283697,0.0008998085],"category_scores_gemma":[0.0003410493,0.0001099919,0.0000774546,0.0001471092,0.0001673571,0.0001585685,0.0001387856,0.0003033488,0.0002532544],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000379247,"about_ca_system_score_gemma":0.000226255,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00182821,"about_ca_topic_score_gemma":0.003074532,"domain_scores_codex":[0.9999133,0.000008512484,0.000005630906,0.00002432905,0.00003456668,0.00001369977],"domain_scores_gemma":[0.9999008,0.00001010102,0.00002597301,0.000006303237,0.00003719284,0.00001962502],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004942663,0.000008036246,0.0001980266,0.00004876984,0.000003324398,0.00001456834,0.00001259429,0.00005663879,0.9980087,0.00006110893,0.00004781082,0.00149115],"study_design_scores_gemma":[0.000004044475,0.00006666817,0.001059028,0.000002904067,0.00000573222,0.00007952562,0.00001989793,0.0003739204,0.9971896,0.00001791421,0.001178017,0.000002754323],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9877335,0.001932049,0.006567235,0.0001078714,0.00003435199,0.0000695871,0.0004456683,0.0001202361,0.0029895],"genre_scores_gemma":[0.9916134,0.0006443532,0.004823137,0.00003251429,0.000008033013,0.00003852336,0.0004697579,0.00002459007,0.00234558],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00182821,"threshold_uncertainty_score":0.003635108,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01467193043407758,"score_gpt":0.189595869574181,"score_spread":0.1749239391401034,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}