{"id":"W1973361127","doi":"10.1021/pr201092v","title":"Precision of Heavy–Light Peptide Ratios Measured by MALDI-TOF Mass Spectrometry","year":2012,"lang":"en","type":"article","venue":"Journal of Proteome Research","topic":"Advanced Proteomics Techniques and Applications","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"National Cancer Institute","keywords":"Peptide; Chemistry; Chromatography; Mass spectrometry; Isotope dilution; Standard curve; Analytical Chemistry (journal); Dilution; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003154477,0.000156095,0.0003682369,0.0003149721,0.0001536281,0.00004066724,0.0006243038,0.0001823792,0.0007447779],"category_scores_gemma":[0.0005730829,0.0001293616,0.0001715623,0.0005758495,0.0001149978,0.0003973412,0.0001218543,0.001193231,0.00002325252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002942414,"about_ca_system_score_gemma":0.0001582777,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008307625,"about_ca_topic_score_gemma":3.43125e-7,"domain_scores_codex":[0.9969307,0.000120928,0.000787949,0.0001808538,0.001409872,0.0005697453],"domain_scores_gemma":[0.9975929,0.0001907873,0.0005276233,0.0004890802,0.0008958234,0.0003038341],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002076095,0.000250716,0.001450681,0.0001246202,0.00003788387,0.000002847637,0.0000780444,0.000003079825,0.9915783,0.0003983056,0.005028759,0.0008391276],"study_design_scores_gemma":[0.0003894287,0.0001559743,0.0001183104,0.0001695282,0.00001062322,0.00005334651,0.0001252076,0.0000205467,0.9775433,0.005505527,0.01578575,0.0001224791],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8081408,0.004421945,0.1651236,0.003378663,0.00008493903,0.00145239,0.00008597441,0.00006811646,0.01724363],"genre_scores_gemma":[0.8407851,0.000373584,0.1560436,0.000007428587,0.0004425218,0.0001070778,0.000004652341,0.00004190363,0.002194187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03264431,"threshold_uncertainty_score":0.8154796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0502299800637798,"score_gpt":0.3752413097686423,"score_spread":0.3250113297048625,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}