{"id":"W1973510998","doi":"10.1002/chem.200801402","title":"Solvent‐Mediated Generation of Cobalt‐Cluster‐Stabilised Propargyl Cations and Radicals: Allyl Migration versus Peroxide Formation","year":2008,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; University College Dublin; Science Foundation Ireland; McMaster University","keywords":"Protonation; Chemistry; Medicinal chemistry; Propargyl; Cationic polymerization; Peroxide; Cobalt; Moiety; Allene; Alkyne; Fluorene; Radical; Solvent; Photochemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003804475,0.0001868887,0.000231105,0.00004410039,0.0003370502,0.00007103423,0.0002058578,0.00005115243,0.002777017],"category_scores_gemma":[0.0003250568,0.0001767999,0.0001279849,0.0001301043,0.0001473959,0.0002673659,0.0000578581,0.0002272991,0.00001213363],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001040646,"about_ca_system_score_gemma":0.00009419418,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003503335,"about_ca_topic_score_gemma":0.000004036172,"domain_scores_codex":[0.9985014,0.00008753662,0.000665236,0.0002245812,0.0003221844,0.0001990713],"domain_scores_gemma":[0.9987978,0.00007965321,0.0004673282,0.0002781976,0.0001784405,0.000198543],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006746087,0.0001145843,0.0001539056,0.00009720682,0.00006893591,0.00001496988,0.0007238478,0.00004454519,0.995046,0.000002517084,0.0006547059,0.003011334],"study_design_scores_gemma":[0.004972934,0.00008608598,0.001768849,0.0001456479,0.0003166323,0.001154712,0.001279988,0.03452815,0.9238164,0.00001077277,0.03128886,0.0006309383],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939504,0.0004527713,0.001313064,0.00035125,0.00004534402,0.00005297385,0.00002968012,0.00003753446,0.00376693],"genre_scores_gemma":[0.9976164,0.0005630762,0.000523889,0.00001592412,0.0003832773,0.000005343981,0.0002808741,0.00002926071,0.0005820011],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07122955,"threshold_uncertainty_score":0.9981346,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04912463469427567,"score_gpt":0.2248423822233667,"score_spread":0.175717747529091,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}