{"id":"W1973561203","doi":"10.1021/om030311t","title":"Pyridine− and Imidazole−Phosphinimine Bidentate Ligand Complexes:  Considerations for Ethylene Oligomerization Catalysts","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":118,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Goddard Space Flight Center","keywords":"Chemistry; Denticity; Pyridine; Ligand (biochemistry); Imidazole; Diphenylphosphine; Medicinal chemistry; Phosphine; Aryl; Catalysis; Chelation; Ethylene; Stereochemistry; Alkyl; Crystallography; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000269054,0.0003361218,0.0002070382,0.0001399878,0.0001999587,0.000576781,0.0005570503,0.0003507392,0.001868242],"category_scores_gemma":[0.000275182,0.0002105052,0.0001286476,0.0001279773,0.0001705881,0.0004493949,0.0002504218,0.0004290403,0.0004576421],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006295395,"about_ca_system_score_gemma":0.000227689,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008344738,"about_ca_topic_score_gemma":0.00201844,"domain_scores_codex":[0.9998564,0.000026453,0.000010891,0.00002852728,0.00003975962,0.00003800259],"domain_scores_gemma":[0.9999321,0.00002227854,0.00001007395,0.00001123726,0.00001097628,0.00001328027],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003524708,0.0001031841,0.0004973374,0.0004120654,0.00001768763,0.0002344133,0.0001800479,0.001995948,0.9793427,0.006749316,0.0003414115,0.009773361],"study_design_scores_gemma":[0.00002183339,0.0002289592,0.0005265428,0.00001781194,0.00001502933,0.0001781837,0.00005818818,0.004849811,0.9861812,0.0002930858,0.007617495,0.0000118169],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9741011,0.002409403,0.01252862,0.0001936788,0.00003600645,0.00008605761,0.0001674335,0.0001743718,0.01030323],"genre_scores_gemma":[0.9866476,0.001020383,0.006957417,0.00004752197,0.000006804147,0.00006348998,0.0002099243,0.00003716478,0.005009728],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001868242,"threshold_uncertainty_score":0.006249905,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02614378281190133,"score_gpt":0.2440325769605226,"score_spread":0.2178887941486213,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}