{"id":"W1973561203","doi":"10.1021/om030311t","title":"Pyridine− and Imidazole−Phosphinimine Bidentate Ligand Complexes:  Considerations for Ethylene Oligomerization Catalysts","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":118,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Goddard Space Flight Center","keywords":"Chemistry; Denticity; Pyridine; Ligand (biochemistry); Imidazole; Diphenylphosphine; Medicinal chemistry; Phosphine; Aryl; Catalysis; Chelation; Ethylene; Stereochemistry; Alkyl; Crystallography; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002571606,0.0003714628,0.0005603781,0.0001338508,0.0004110461,0.000223465,0.000165227,0.0001386228,0.007044621],"category_scores_gemma":[0.0009002854,0.0003759902,0.0001757423,0.0004180434,0.0001744517,0.0002371502,0.00007557193,0.0001283557,0.0000414633],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006425576,"about_ca_system_score_gemma":0.00009759484,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002534316,"about_ca_topic_score_gemma":0.00005629431,"domain_scores_codex":[0.9981112,0.00002552865,0.0005955963,0.0005977742,0.0002539337,0.0004159713],"domain_scores_gemma":[0.9982975,0.0005116848,0.000241085,0.0005640654,0.000160362,0.0002253346],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001764227,0.0002320377,0.001222621,0.0002439753,0.0003929756,0.000006123251,0.0005618929,0.00003918633,0.9764087,0.01828969,0.0002478249,0.002337308],"study_design_scores_gemma":[0.001095465,0.00003818345,0.00105913,0.00003718894,0.0005264018,0.00008384632,0.0006433045,0.0003616422,0.9450884,0.004177873,0.04614453,0.0007440162],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903462,0.001345834,0.001155267,0.0005634247,0.0001221689,0.0002643123,0.0002652275,0.0001550038,0.00578257],"genre_scores_gemma":[0.9944815,0.0005001615,0.002202626,0.0001635384,0.0001057488,0.00008437413,0.0002690383,0.00009347826,0.002099512],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04589671,"threshold_uncertainty_score":0.9998692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02614378281190133,"score_gpt":0.2440325769605226,"score_spread":0.2178887941486213,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}