{"id":"W1973904699","doi":"10.1002/chem.200801530","title":"Rapid Ketone Transfer Hydrogenation by Employing Simple, In Situ Prepared Iridium(I) Precatalysts Supported by “Non‐NH” P,N Ligands","year":2008,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Acetophenone; Indene; Chemistry; Catalysis; Transfer hydrogenation; Iridium; Medicinal chemistry; Ligand (biochemistry); Ketone; Trifluoromethanesulfonate; Stereochemistry; Organic chemistry; Ruthenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009826934,0.0004085357,0.0002278531,0.00008337686,0.00009516212,0.0002748386,0.0004450442,0.0002578107,0.0009325792],"category_scores_gemma":[0.0001914609,0.0001784294,0.000124386,0.000100205,0.0002232566,0.0003467069,0.0002948818,0.0004855755,0.0002930807],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002185661,"about_ca_system_score_gemma":0.0001519998,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004593385,"about_ca_topic_score_gemma":0.000908195,"domain_scores_codex":[0.999915,0.000007895307,0.000007393057,0.00002273216,0.00002442515,0.00002256139],"domain_scores_gemma":[0.9999417,0.0000109009,0.00002120589,0.00000852079,0.000007915135,0.000009742265],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009986712,0.00001067159,0.00006626465,0.0001134408,0.000008121821,0.00005918206,0.00004959827,0.00008510464,0.9965698,0.0002350998,0.0001059007,0.002596952],"study_design_scores_gemma":[0.000006076658,0.00005534551,0.000170209,0.000002320243,0.000005428355,0.00007142816,0.000009266796,0.0002209925,0.9983347,0.00001678394,0.001104141,0.000003308668],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9809216,0.001501213,0.01053627,0.00009061724,0.00006997985,0.00005422445,0.0001867562,0.0004335328,0.006205816],"genre_scores_gemma":[0.993767,0.000635569,0.003669789,0.00002613645,0.00000730728,0.00001841066,0.0001143623,0.00004044512,0.001720914],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009325792,"threshold_uncertainty_score":0.003119767,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01304327890976519,"score_gpt":0.2192964405643353,"score_spread":0.2062531616545701,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}