{"id":"W1973954646","doi":"10.1021/ic040077e","title":"Transformation of μ<sub>4</sub>-Phosphinidenes at an Ru<sub>5</sub> Center:  Isolation and Structural Characterization of Hydroxyphosphinidene Cluster Acids, Fluorophosphinidenes, and a Novel μ<sub>5</sub>-Phosphide","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; University of Regina; Steacie Institute for Molecular Sciences; University of Ottawa","funders":"","keywords":"Chemistry; Ruthenium; Cationic polymerization; Protonation; Cluster (spacecraft); Phosphide; Stereochemistry; Hydride; Hydrolysis; Crystallography; Medicinal chemistry; Hydrogen; Metal; Catalysis; Ion; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005974259,0.0001974799,0.0001240181,0.00009476106,0.00007646824,0.0001788817,0.000235184,0.0001794234,0.0008910644],"category_scores_gemma":[0.0001320824,0.00009819411,0.00009946694,0.000094324,0.0001263327,0.0001566032,0.0001679481,0.0001747287,0.0002239273],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001925096,"about_ca_system_score_gemma":0.0001158323,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000539717,"about_ca_topic_score_gemma":0.0006378423,"domain_scores_codex":[0.9999405,0.000006828107,0.00000390906,0.00001314125,0.00002169248,0.0000138355],"domain_scores_gemma":[0.9999611,0.000004596566,0.00001309324,0.000004712158,0.000006922006,0.000009482163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008495882,0.000009189292,0.0001678142,0.00003721816,0.00000547845,0.00004276163,0.0000183749,0.0001400308,0.9969516,0.0001593299,0.00003248452,0.00235075],"study_design_scores_gemma":[0.000003500193,0.00007056724,0.0006383104,0.000001049874,0.000003897221,0.00005689771,0.00000921546,0.0002607645,0.9978693,0.00001706457,0.001067884,0.000001590474],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938726,0.0004830847,0.003134517,0.00002689531,0.000007492158,0.0000206153,0.0001260138,0.00007809741,0.002250615],"genre_scores_gemma":[0.9965617,0.0001586904,0.001551363,0.00001682885,0.00000230188,0.000009603211,0.0001889975,0.00001377842,0.001496794],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008910644,"threshold_uncertainty_score":0.002980888,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006194029197223213,"score_gpt":0.1933043402660079,"score_spread":0.1871103110687847,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}